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Synthesis and Characterization of a Crystalline Imine-Based Covalent Organic Framework with Triazine Node and Biphenyl Linker and Its Fluorinated Derivate for CO(2)/CH(4) Separation
A catalyst-free Schiff base reaction was applied to synthesize two imine-linked covalent organic frameworks (COFs). The condensation reaction of 1,3,5-tris-(4-aminophenyl)triazine (TAPT) with 4,4′-biphenyldicarboxaldehyde led to the structure of HHU-COF-1 (HHU = Heinrich-Heine University). The fluor...
Autores principales: | Bügel, Stefanie, Hähnel, Malte, Kunde, Tom, de Sousa Amadeu, Nader, Sun, Yangyang, Spieß, Alex, Beglau, Thi Hai Yen, Schmidt, Bernd M., Janiak, Christoph |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9031922/ https://www.ncbi.nlm.nih.gov/pubmed/35454500 http://dx.doi.org/10.3390/ma15082807 |
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