Selectivity for water isotopologues within metal organic nanotubes

Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake...

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Detalles Bibliográficos
Autores principales: Payne, Maurice K., Applegate, Lindsey C., Singh, Priyanka, Jayasinghe, Ashini S., Crull, George B., Grafton, Andrea B., Cheatum, Christopher M., Forbes, Tori Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9032102/
https://www.ncbi.nlm.nih.gov/pubmed/35479164
http://dx.doi.org/10.1039/d1ra00602a
Descripción
Sumario:Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.