Selectivity for water isotopologues within metal organic nanotubes
Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9032102/ https://www.ncbi.nlm.nih.gov/pubmed/35479164 http://dx.doi.org/10.1039/d1ra00602a |
Sumario: | Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material. |
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