Selectivity for water isotopologues within metal organic nanotubes

Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake...

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Autores principales: Payne, Maurice K., Applegate, Lindsey C., Singh, Priyanka, Jayasinghe, Ashini S., Crull, George B., Grafton, Andrea B., Cheatum, Christopher M., Forbes, Tori Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9032102/
https://www.ncbi.nlm.nih.gov/pubmed/35479164
http://dx.doi.org/10.1039/d1ra00602a
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author Payne, Maurice K.
Applegate, Lindsey C.
Singh, Priyanka
Jayasinghe, Ashini S.
Crull, George B.
Grafton, Andrea B.
Cheatum, Christopher M.
Forbes, Tori Z.
author_facet Payne, Maurice K.
Applegate, Lindsey C.
Singh, Priyanka
Jayasinghe, Ashini S.
Crull, George B.
Grafton, Andrea B.
Cheatum, Christopher M.
Forbes, Tori Z.
author_sort Payne, Maurice K.
collection PubMed
description Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.
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spelling pubmed-90321022022-04-26 Selectivity for water isotopologues within metal organic nanotubes Payne, Maurice K. Applegate, Lindsey C. Singh, Priyanka Jayasinghe, Ashini S. Crull, George B. Grafton, Andrea B. Cheatum, Christopher M. Forbes, Tori Z. RSC Adv Chemistry Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H(2)O over all types of heavy water (D(2)O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material. The Royal Society of Chemistry 2021-05-06 /pmc/articles/PMC9032102/ /pubmed/35479164 http://dx.doi.org/10.1039/d1ra00602a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Payne, Maurice K.
Applegate, Lindsey C.
Singh, Priyanka
Jayasinghe, Ashini S.
Crull, George B.
Grafton, Andrea B.
Cheatum, Christopher M.
Forbes, Tori Z.
Selectivity for water isotopologues within metal organic nanotubes
title Selectivity for water isotopologues within metal organic nanotubes
title_full Selectivity for water isotopologues within metal organic nanotubes
title_fullStr Selectivity for water isotopologues within metal organic nanotubes
title_full_unstemmed Selectivity for water isotopologues within metal organic nanotubes
title_short Selectivity for water isotopologues within metal organic nanotubes
title_sort selectivity for water isotopologues within metal organic nanotubes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9032102/
https://www.ncbi.nlm.nih.gov/pubmed/35479164
http://dx.doi.org/10.1039/d1ra00602a
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