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A new family of decanuclear Ln(7)Cr(3) clusters exhibiting a magnetocaloric effect
Two dimeric Ln–Cr clusters with formula {Ln(H(2)O)(8)[Ln(6)Cr(3)(L)(6)(CH(3)COO)(6)(μ(3)-OH)(12)(H(2)O)(12)]}·(ClO(4))(6)·xH(2)O (Ln = Gd, x = 35 for 1 and Ln = Dy, x = 45 for 2, HL = 2-pyrazinecarboxylic acid) were obtained by a ligand-controlled hydrolytic method with a mixed ligand system (2-pyra...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033162/ https://www.ncbi.nlm.nih.gov/pubmed/35479672 http://dx.doi.org/10.1039/d1ra02734d |