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A new family of decanuclear Ln(7)Cr(3) clusters exhibiting a magnetocaloric effect

Two dimeric Ln–Cr clusters with formula {Ln(H(2)O)(8)[Ln(6)Cr(3)(L)(6)(CH(3)COO)(6)(μ(3)-OH)(12)(H(2)O)(12)]}·(ClO(4))(6)·xH(2)O (Ln = Gd, x = 35 for 1 and Ln = Dy, x = 45 for 2, HL = 2-pyrazinecarboxylic acid) were obtained by a ligand-controlled hydrolytic method with a mixed ligand system (2-pyra...

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Detalles Bibliográficos
Autores principales: Yin, Jia-Jia, Lu, Tian-Qi, Chen, Cheng, Shi, Hai-Yan, Zhuang, Gui-Lin, Zheng, Jun, Fang, Xiaolong, Zheng, Xiu-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033162/
https://www.ncbi.nlm.nih.gov/pubmed/35479672
http://dx.doi.org/10.1039/d1ra02734d

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