Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Three new thorium-based MOFs based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under a similar reaction system (metal salt, ligand, solvent, and acid are the same). Th(iv) forms the central unit of the MOFs in mononuclear and binuclear clusters, respectively. All the MOFs show...

Descripción completa

Detalles Bibliográficos
Autores principales: Yu, Ting, Qian, Zheng-hua, Li, Lin, Wu, Xiao-ling, He, Hui, Qiao, Yan-bo, Ye, Guo-an
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033178/
https://www.ncbi.nlm.nih.gov/pubmed/35479668
http://dx.doi.org/10.1039/d1ra01742j
Descripción
Sumario:Three new thorium-based MOFs based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under a similar reaction system (metal salt, ligand, solvent, and acid are the same). Th(iv) forms the central unit of the MOFs in mononuclear and binuclear clusters, respectively. All the MOFs show blue ligand-based luminescence under an ultraviolet environment. This is the first time that multiple thorium-based MOFs with luminescence have been found with the same ligand.

Ejemplares similares