Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Three new thorium-based MOFs based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under a similar reaction system (metal salt, ligand, solvent, and acid are the same). Th(iv) forms the central unit of the MOFs in mononuclear and binuclear clusters, respectively. All the MOFs show...

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Detalles Bibliográficos
Autores principales: Yu, Ting, Qian, Zheng-hua, Li, Lin, Wu, Xiao-ling, He, Hui, Qiao, Yan-bo, Ye, Guo-an
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033178/
https://www.ncbi.nlm.nih.gov/pubmed/35479668
http://dx.doi.org/10.1039/d1ra01742j
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author Yu, Ting
Qian, Zheng-hua
Li, Lin
Wu, Xiao-ling
He, Hui
Qiao, Yan-bo
Ye, Guo-an
author_facet Yu, Ting
Qian, Zheng-hua
Li, Lin
Wu, Xiao-ling
He, Hui
Qiao, Yan-bo
Ye, Guo-an
author_sort Yu, Ting
collection PubMed
description Three new thorium-based MOFs based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under a similar reaction system (metal salt, ligand, solvent, and acid are the same). Th(iv) forms the central unit of the MOFs in mononuclear and binuclear clusters, respectively. All the MOFs show blue ligand-based luminescence under an ultraviolet environment. This is the first time that multiple thorium-based MOFs with luminescence have been found with the same ligand.
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spelling pubmed-90331782022-04-26 Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene Yu, Ting Qian, Zheng-hua Li, Lin Wu, Xiao-ling He, Hui Qiao, Yan-bo Ye, Guo-an RSC Adv Chemistry Three new thorium-based MOFs based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under a similar reaction system (metal salt, ligand, solvent, and acid are the same). Th(iv) forms the central unit of the MOFs in mononuclear and binuclear clusters, respectively. All the MOFs show blue ligand-based luminescence under an ultraviolet environment. This is the first time that multiple thorium-based MOFs with luminescence have been found with the same ligand. The Royal Society of Chemistry 2021-05-12 /pmc/articles/PMC9033178/ /pubmed/35479668 http://dx.doi.org/10.1039/d1ra01742j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Yu, Ting
Qian, Zheng-hua
Li, Lin
Wu, Xiao-ling
He, Hui
Qiao, Yan-bo
Ye, Guo-an
Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
title Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
title_full Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
title_fullStr Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
title_full_unstemmed Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
title_short Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
title_sort synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033178/
https://www.ncbi.nlm.nih.gov/pubmed/35479668
http://dx.doi.org/10.1039/d1ra01742j
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