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Silylative aromatization of p-quinone methides under metal and solvent free conditions
A base-mediated silylation reaction leading to benzyl silanes has been developed. Under transition-metal and solvent free conditions, the silylation of a wide array of p-quinone methides is achieved using a Cs(2)CO(3) catalyst in yields up to 96%. Carboxylation of the as-obtained organosilane with g...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033227/ https://www.ncbi.nlm.nih.gov/pubmed/35480172 http://dx.doi.org/10.1039/d1ra03193g |
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author | Li, Tingting Wu, Yuzhu Duan, Wenzeng Ma, Yudao |
author_facet | Li, Tingting Wu, Yuzhu Duan, Wenzeng Ma, Yudao |
author_sort | Li, Tingting |
collection | PubMed |
description | A base-mediated silylation reaction leading to benzyl silanes has been developed. Under transition-metal and solvent free conditions, the silylation of a wide array of p-quinone methides is achieved using a Cs(2)CO(3) catalyst in yields up to 96%. Carboxylation of the as-obtained organosilane with gaseous CO(2) provides a new synthetic protocol for the preparation of carboxylic acid. |
format | Online Article Text |
id | pubmed-9033227 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90332272022-04-26 Silylative aromatization of p-quinone methides under metal and solvent free conditions Li, Tingting Wu, Yuzhu Duan, Wenzeng Ma, Yudao RSC Adv Chemistry A base-mediated silylation reaction leading to benzyl silanes has been developed. Under transition-metal and solvent free conditions, the silylation of a wide array of p-quinone methides is achieved using a Cs(2)CO(3) catalyst in yields up to 96%. Carboxylation of the as-obtained organosilane with gaseous CO(2) provides a new synthetic protocol for the preparation of carboxylic acid. The Royal Society of Chemistry 2021-05-18 /pmc/articles/PMC9033227/ /pubmed/35480172 http://dx.doi.org/10.1039/d1ra03193g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Li, Tingting Wu, Yuzhu Duan, Wenzeng Ma, Yudao Silylative aromatization of p-quinone methides under metal and solvent free conditions |
title | Silylative aromatization of p-quinone methides under metal and solvent free conditions |
title_full | Silylative aromatization of p-quinone methides under metal and solvent free conditions |
title_fullStr | Silylative aromatization of p-quinone methides under metal and solvent free conditions |
title_full_unstemmed | Silylative aromatization of p-quinone methides under metal and solvent free conditions |
title_short | Silylative aromatization of p-quinone methides under metal and solvent free conditions |
title_sort | silylative aromatization of p-quinone methides under metal and solvent free conditions |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033227/ https://www.ncbi.nlm.nih.gov/pubmed/35480172 http://dx.doi.org/10.1039/d1ra03193g |
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