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Silylative aromatization of p-quinone methides under metal and solvent free conditions
A base-mediated silylation reaction leading to benzyl silanes has been developed. Under transition-metal and solvent free conditions, the silylation of a wide array of p-quinone methides is achieved using a Cs(2)CO(3) catalyst in yields up to 96%. Carboxylation of the as-obtained organosilane with g...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033227/ https://www.ncbi.nlm.nih.gov/pubmed/35480172 http://dx.doi.org/10.1039/d1ra03193g |