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Silylative aromatization of p-quinone methides under metal and solvent free conditions

A base-mediated silylation reaction leading to benzyl silanes has been developed. Under transition-metal and solvent free conditions, the silylation of a wide array of p-quinone methides is achieved using a Cs(2)CO(3) catalyst in yields up to 96%. Carboxylation of the as-obtained organosilane with g...

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Detalles Bibliográficos
Autores principales:	Li, Tingting, Wu, Yuzhu, Duan, Wenzeng, Ma, Yudao
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033227/ https://www.ncbi.nlm.nih.gov/pubmed/35480172 http://dx.doi.org/10.1039/d1ra03193g

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