Tubular g-C(3)N(4)/carbon framework for high-efficiency photocatalytic degradation of methylene blue

The preparation of high-efficiency, pollution-free photocatalysts for water treatment has always been one of the research hotspots. In this paper, a carbon framework formed from waste grapefruit peel is used as the carrier. A simple one-step chemical vapor deposition (CVD) method allows tubular g-C(3)N(4) to grow on the carbon framework. Tubular g-C(3)N(4) increases the specific surface area of bulk g-C(3)N(4) and enhances the absorption of visible light. At the same time, the carbon framework can effectively promote the separation and transfer of charges. The dual effects of static adsorption and photodegradation enable the g-C(3)N(4)/carbon (CNC) framework to quickly remove about 98% of methylene blue within 180 min. The recyclability indicates that the tubular g-C(3)N(4) can stably exist on the carbon framework during the photodegradation process. In the dynamic photocatalytic test driven by gravity, roughly 77.65% of the methylene blue was degraded by the CNC framework. Our work provides an attractive strategy for constructing a composite carbon framework photocatalyst based on the tubular g-C(3)N(4) structure and improving the photocatalytic performance.