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Organic–inorganic interactions revealed by Raman spectroscopy during reversible phase transitions in semiconducting [(C(2)H(5))(4)N]FeCl(4)

The alkylammonium halogenoferrate families are subjected to diverse studies according to their wide field application. However, these compounds show various transitions depending on the preparation process. In this paper, the [(C(2)H(5))(4)N]FeCl(4) compound was successfully synthesized using a slow...

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Detalles Bibliográficos
Autores principales: Ben Brahim, Khaoula, Ben gzaiel, Malika, Oueslati, Abderrazek, Khirouni, Kamel, Gargouri, Mohamed., Corbel, Gwenaël, Bardeau, Jean-François
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033484/
https://www.ncbi.nlm.nih.gov/pubmed/35480942
http://dx.doi.org/10.1039/d1ra02475b
Descripción
Sumario:The alkylammonium halogenoferrate families are subjected to diverse studies according to their wide field application. However, these compounds show various transitions depending on the preparation process. In this paper, the [(C(2)H(5))(4)N]FeCl(4) compound was successfully synthesized using a slow evaporation solution growth method at room temperature. An optical absorption measurement confirms the semiconductor nature with a band gap around 2.95 eV. The X-ray powder diffraction (XRPD) data confirmed the formation of a single-phase with hexagonal-type structure. The differential scanning calorimetry (DSC) indicated that the [(C(2)H(5))(4)N]FeCl(4) compound undergoes eight reversible phase transitions between 193 and 443 K. At high temperature (T > 423 K) the plastic nature of the crystals was confirmed. Temperature-controlled X-ray diffraction reveals that the thermal expansion of the crystal structure is non homothetic in the (a,b) plane and along the c axis. The temperature dependence of the Raman spectra up to 443 K revealed specific reorientations and molecular displacements of the organic and inorganic components associated with the phase transitions. We aim to thermally stabilize the [(C(2)H(5))(4)N]FeCl(4) compound which has a band gap suitable for photocatalytic processes.