Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups

The first synthesis of 5,12-diamino-7,14-bis(aryl)-1,4,8,11-tetrathiacyclotetradeca-5,12-diene-6,13-dicarbonitriles was performed as a multicomponent macroheterocyclization of malononitrile, aryl aldehydes, and 1,2-ethanedithiol in the presence of a catalytic amount of triethylamine in ethanol. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Akhmadiev, Nail S., Mescheryakova, Ekaterina S., Akhmetova, Vnira R., Ibragimov, Askhat G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033490/
https://www.ncbi.nlm.nih.gov/pubmed/35478647
http://dx.doi.org/10.1039/d1ra02616j
_version_ 1784692901619433472
author Akhmadiev, Nail S.
Mescheryakova, Ekaterina S.
Akhmetova, Vnira R.
Ibragimov, Askhat G.
author_facet Akhmadiev, Nail S.
Mescheryakova, Ekaterina S.
Akhmetova, Vnira R.
Ibragimov, Askhat G.
author_sort Akhmadiev, Nail S.
collection PubMed
description The first synthesis of 5,12-diamino-7,14-bis(aryl)-1,4,8,11-tetrathiacyclotetradeca-5,12-diene-6,13-dicarbonitriles was performed as a multicomponent macroheterocyclization of malononitrile, aryl aldehydes, and 1,2-ethanedithiol in the presence of a catalytic amount of triethylamine in ethanol. The structures of the obtained macroheterocycles were confirmed by spectral methods, X-ray diffraction, and MALDI TOF mass spectrometry.
format Online
Article
Text
id pubmed-9033490
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90334902022-04-26 Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups Akhmadiev, Nail S. Mescheryakova, Ekaterina S. Akhmetova, Vnira R. Ibragimov, Askhat G. RSC Adv Chemistry The first synthesis of 5,12-diamino-7,14-bis(aryl)-1,4,8,11-tetrathiacyclotetradeca-5,12-diene-6,13-dicarbonitriles was performed as a multicomponent macroheterocyclization of malononitrile, aryl aldehydes, and 1,2-ethanedithiol in the presence of a catalytic amount of triethylamine in ethanol. The structures of the obtained macroheterocycles were confirmed by spectral methods, X-ray diffraction, and MALDI TOF mass spectrometry. The Royal Society of Chemistry 2021-05-25 /pmc/articles/PMC9033490/ /pubmed/35478647 http://dx.doi.org/10.1039/d1ra02616j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Akhmadiev, Nail S.
Mescheryakova, Ekaterina S.
Akhmetova, Vnira R.
Ibragimov, Askhat G.
Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
title Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
title_full Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
title_fullStr Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
title_full_unstemmed Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
title_short Metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
title_sort metal-free multicomponent synthesis of novel macrocyclic tetrathiadienes with cyano and amino groups
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033490/
https://www.ncbi.nlm.nih.gov/pubmed/35478647
http://dx.doi.org/10.1039/d1ra02616j
work_keys_str_mv AT akhmadievnails metalfreemulticomponentsynthesisofnovelmacrocyclictetrathiadieneswithcyanoandaminogroups
AT mescheryakovaekaterinas metalfreemulticomponentsynthesisofnovelmacrocyclictetrathiadieneswithcyanoandaminogroups
AT akhmetovavnirar metalfreemulticomponentsynthesisofnovelmacrocyclictetrathiadieneswithcyanoandaminogroups
AT ibragimovaskhatg metalfreemulticomponentsynthesisofnovelmacrocyclictetrathiadieneswithcyanoandaminogroups

Ejemplares similares