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Phenylphosphonate surface functionalisation of MgMn(2)O(4) with 3D open-channel nanostructures for composite slurry-coated cathodes of rechargeable magnesium batteries operated at room temperature
Spinel-type MgMn(2)O(4), prepared by a propylene-oxide-driven sol–gel method, has a high surface area and structured bimodal macro- and mesopores, and exhibits good electrochemical properties as a cathode active material for rechargeable magnesium batteries. However, because of its hydrophilicity an...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033493/ https://www.ncbi.nlm.nih.gov/pubmed/35478634 http://dx.doi.org/10.1039/d1ra02598h |
Sumario: | Spinel-type MgMn(2)O(4), prepared by a propylene-oxide-driven sol–gel method, has a high surface area and structured bimodal macro- and mesopores, and exhibits good electrochemical properties as a cathode active material for rechargeable magnesium batteries. However, because of its hydrophilicity and significant water adsorption properties, macroscopic aggregates are formed in composite slurry-coated cathodes when 1-methyl-2-pyrrolidone (NMP) is used as a non-aqueous solvent. Functionalising the surface with phenylphosphonate groups was found to be an easy and effective technique to render the structured MgMn(2)O(4) hydrophobic and suppress aggregate formation in NMP-based slurries. This surface functionalisation also reduced side reactions during charging, while maintaining the discharge capacity, and significantly improved the coulombic efficiency. Uniform slurry-coated cathodes with active material fractions as high as 93 wt% can be produced on Al foils by this technique employing carbon nanotubes as an electrically conductive support. A coin-type full cell consisting of this slurry-coated cathode and a magnesium alloy anode delivered an initial discharge capacity of ∼100 mA h g(−1) at 25 °C. |
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