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A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor

A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regar...

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Detalles Bibliográficos
Autores principales: Tareen, Ayesha Khan, Khan, Karim, Ahmad, Waqas, Khan, Muhammad Farooq, Khan, Qudrat Ullah, Liu, Xinke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033555/
https://www.ncbi.nlm.nih.gov/pubmed/35478651
http://dx.doi.org/10.1039/d1ra01485d
Descripción
Sumario:A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H(2)O(2)) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R(2)) value of 0.995. Excellent performance toward H(2)O(2) was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM(−1) cm(−2). A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H(2)O(2) sensing.