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A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regar...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033555/ https://www.ncbi.nlm.nih.gov/pubmed/35478651 http://dx.doi.org/10.1039/d1ra01485d |
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author | Tareen, Ayesha Khan Khan, Karim Ahmad, Waqas Khan, Muhammad Farooq Khan, Qudrat Ullah Liu, Xinke |
author_facet | Tareen, Ayesha Khan Khan, Karim Ahmad, Waqas Khan, Muhammad Farooq Khan, Qudrat Ullah Liu, Xinke |
author_sort | Tareen, Ayesha Khan |
collection | PubMed |
description | A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H(2)O(2)) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R(2)) value of 0.995. Excellent performance toward H(2)O(2) was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM(−1) cm(−2). A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H(2)O(2) sensing. |
format | Online Article Text |
id | pubmed-9033555 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90335552022-04-26 A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor Tareen, Ayesha Khan Khan, Karim Ahmad, Waqas Khan, Muhammad Farooq Khan, Qudrat Ullah Liu, Xinke RSC Adv Chemistry A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H(2)O(2)) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R(2)) value of 0.995. Excellent performance toward H(2)O(2) was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM(−1) cm(−2). A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H(2)O(2) sensing. The Royal Society of Chemistry 2021-05-27 /pmc/articles/PMC9033555/ /pubmed/35478651 http://dx.doi.org/10.1039/d1ra01485d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Tareen, Ayesha Khan Khan, Karim Ahmad, Waqas Khan, Muhammad Farooq Khan, Qudrat Ullah Liu, Xinke A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor |
title | A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor |
title_full | A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor |
title_fullStr | A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor |
title_full_unstemmed | A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor |
title_short | A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor |
title_sort | novel mno–crn nanocomposite based non-enzymatic hydrogen peroxide sensor |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033555/ https://www.ncbi.nlm.nih.gov/pubmed/35478651 http://dx.doi.org/10.1039/d1ra01485d |
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