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A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor

A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regar...

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Autores principales: Tareen, Ayesha Khan, Khan, Karim, Ahmad, Waqas, Khan, Muhammad Farooq, Khan, Qudrat Ullah, Liu, Xinke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033555/
https://www.ncbi.nlm.nih.gov/pubmed/35478651
http://dx.doi.org/10.1039/d1ra01485d
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author Tareen, Ayesha Khan
Khan, Karim
Ahmad, Waqas
Khan, Muhammad Farooq
Khan, Qudrat Ullah
Liu, Xinke
author_facet Tareen, Ayesha Khan
Khan, Karim
Ahmad, Waqas
Khan, Muhammad Farooq
Khan, Qudrat Ullah
Liu, Xinke
author_sort Tareen, Ayesha Khan
collection PubMed
description A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H(2)O(2)) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R(2)) value of 0.995. Excellent performance toward H(2)O(2) was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM(−1) cm(−2). A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H(2)O(2) sensing.
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spelling pubmed-90335552022-04-26 A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor Tareen, Ayesha Khan Khan, Karim Ahmad, Waqas Khan, Muhammad Farooq Khan, Qudrat Ullah Liu, Xinke RSC Adv Chemistry A MnO–CrN composite was obtained via the ammonolysis of the low-cost nitride precursors Cr(NO(3))(3)·9H(2)O and Mn(NO(3))(2)·4H(2)O at 800 °C for 8 h using a sol–gel method. The specific surface area of the synthesized powder was measured via BET analysis and it was found to be 262 m(2) g(−1). Regarding its application, the electrochemical sensing performance toward hydrogen peroxide (H(2)O(2)) was studied via applying cyclic voltammetry (CV) and amperometry (i–t) analysis. The linear response range was 0.33–15 000 μM with a correlation coefficient (R(2)) value of 0.995. Excellent performance toward H(2)O(2) was observed with a limit of detection of 0.059 μM, a limit of quantification of 0.199 μM, and sensitivity of 2156.25 μA mM(−1) cm(−2). A short response time of within 2 s was achieved. Hence, we develop and offer an efficient approach for synthesizing a new cost-efficient material for H(2)O(2) sensing. The Royal Society of Chemistry 2021-05-27 /pmc/articles/PMC9033555/ /pubmed/35478651 http://dx.doi.org/10.1039/d1ra01485d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Tareen, Ayesha Khan
Khan, Karim
Ahmad, Waqas
Khan, Muhammad Farooq
Khan, Qudrat Ullah
Liu, Xinke
A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
title A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
title_full A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
title_fullStr A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
title_full_unstemmed A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
title_short A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor
title_sort novel mno–crn nanocomposite based non-enzymatic hydrogen peroxide sensor
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033555/
https://www.ncbi.nlm.nih.gov/pubmed/35478651
http://dx.doi.org/10.1039/d1ra01485d
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