Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes

The metal-free DBU catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes proceeded smoothly to furnish the corresponding highly functionalized cyclopentane-fused coumarins with excellent diastereoselectivity and complete chemoselectivity and in good yields under mild conditio...

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Autores principales: Lin, Huawei, Yang, Huimin, Gong, Qi, Luo, Shan, Gu, Jing, Cao, Xiaoqun, Mao, Biming, Ge, Yanqing, Yuan, Chunhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033744/
https://www.ncbi.nlm.nih.gov/pubmed/35479921
http://dx.doi.org/10.1039/d1ra03387e
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author Lin, Huawei
Yang, Huimin
Gong, Qi
Luo, Shan
Gu, Jing
Cao, Xiaoqun
Mao, Biming
Ge, Yanqing
Yuan, Chunhao
author_facet Lin, Huawei
Yang, Huimin
Gong, Qi
Luo, Shan
Gu, Jing
Cao, Xiaoqun
Mao, Biming
Ge, Yanqing
Yuan, Chunhao
author_sort Lin, Huawei
collection PubMed
description The metal-free DBU catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes proceeded smoothly to furnish the corresponding highly functionalized cyclopentane-fused coumarins with excellent diastereoselectivity and complete chemoselectivity and in good yields under mild conditions.
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spelling pubmed-90337442022-04-26 Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes Lin, Huawei Yang, Huimin Gong, Qi Luo, Shan Gu, Jing Cao, Xiaoqun Mao, Biming Ge, Yanqing Yuan, Chunhao RSC Adv Chemistry The metal-free DBU catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes proceeded smoothly to furnish the corresponding highly functionalized cyclopentane-fused coumarins with excellent diastereoselectivity and complete chemoselectivity and in good yields under mild conditions. The Royal Society of Chemistry 2021-06-04 /pmc/articles/PMC9033744/ /pubmed/35479921 http://dx.doi.org/10.1039/d1ra03387e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Lin, Huawei
Yang, Huimin
Gong, Qi
Luo, Shan
Gu, Jing
Cao, Xiaoqun
Mao, Biming
Ge, Yanqing
Yuan, Chunhao
Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
title Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
title_full Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
title_fullStr Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
title_full_unstemmed Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
title_short Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
title_sort construction of cyclopentane-fused coumarins via dbu-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033744/
https://www.ncbi.nlm.nih.gov/pubmed/35479921
http://dx.doi.org/10.1039/d1ra03387e
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