Radiation-initiated high strength chitosan/lithium sulfonate double network hydrogel/aerogel with porosity and stability for efficient CO(2) capture

Developing efficient and inexpensive CO(2) capture technologies is a significant way to reduce carbon emissions. In this work, a novel chitosan/lithium sulfonate double network high strength hydrogel is synthesized by electron beam radiation. Due to the electron beam having a wide radiation area and certain penetrating power, the free radical polymerization can be initiated more uniformly and quickly in the hydrogel. The network structure of the hydrogel prepared by radiation-initiated polymerization is more uniform than that prepared by conventional chemical initiator-initiated polymerization. Meanwhile, the introduction of the second network to construct the double network structure does not reduce the surface area of the aerogel, which is different from the conventional method of grafting or impregnation modified porous materials. Moreover, the synthesized aerogels have good physical and chemical stability. The freeze-dried aerogels possess a porous structure and CO(2) capture ability due to the CO(2)-philic double network structure. Because of the inexpensive raw material and convenient radiation process, this work can reduce the cost of CO(2) adsorbents and has prospects of application in the field of CO(2) solid adsorbents.