Paramagnetic solid-state NMR assignment and novel chemical conversion of the aldehyde group to dihydrogen ortho ester and hemiacetal moieties in copper(ii)- and cobalt(ii)-pyridinecarboxaldehyde complexes

The complex chemical functionalization of aldehyde moieties in Cu(ii)- and Co(ii)-pyridinecarboxaldehyde complexes was studied. X-ray studies demonstrated that the aldehyde group (RCHO) of the four pyridine molecules is converted to dihydrogen ortho ester (RC(OCH(3))(OH)(2)) and hemiacetal (RCH(OH)(...

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Detalles Bibliográficos
Autores principales: Crespi, Ayelén F., Sánchez, Verónica M., Vega, Daniel, Pérez, Ana L., Brondino, Carlos D., Linck, Yamila Garro, Hodgkinson, Paul, Rodríguez-Castellón, Enrique, Lázaro-Martínez, Juan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9033980/
https://www.ncbi.nlm.nih.gov/pubmed/35479880
http://dx.doi.org/10.1039/d1ra02512k

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