Ru(III)(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

The reduction of molecular oxygen (O(2)) and hydrogen peroxide (H(2)O(2)) by [Ru(II)(edta)(pz)](2−) (edta(4−) = ethylenediaminetetraacetate; pz = pyrazine) has been studied spectrophotometrically and kinetically in aqueous solution. Exposure of the aqua-analogue [Ru(II)(edta)(H(2)O)](2−) to O(2) and...

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Detalles Bibliográficos
Autores principales: Chatterjee, Debabrata, Chrzanowska, Marta, Katafias, Anna, Oszajca, Maria, van Eldik, Rudi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034107/
https://www.ncbi.nlm.nih.gov/pubmed/35478799
http://dx.doi.org/10.1039/d1ra03293c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034107/
https://www.ncbi.nlm.nih.gov/pubmed/35478799
http://dx.doi.org/10.1039/d1ra03293c

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