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Ru(III)(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism
The reduction of molecular oxygen (O(2)) and hydrogen peroxide (H(2)O(2)) by [Ru(II)(edta)(pz)](2−) (edta(4−) = ethylenediaminetetraacetate; pz = pyrazine) has been studied spectrophotometrically and kinetically in aqueous solution. Exposure of the aqua-analogue [Ru(II)(edta)(H(2)O)](2−) to O(2) and...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034107/ https://www.ncbi.nlm.nih.gov/pubmed/35478799 http://dx.doi.org/10.1039/d1ra03293c |