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μ-Oxo-bridged diiron(iii) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation

A series of non-heme μ-oxo-bridged dinuclear iron(iii) complexes of the type [Fe(2)(μ-O)(L1–L6)(2)Cl(2)]Cl(2)1–6 have been isolated and their catalytic activity towards oxidative transformation of alkanes into alcohols has been studied using m-choloroperbenzoic acid (m-CPBA) as an oxidant. All the c...

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Detalles Bibliográficos
Autores principales: Balamurugan, Mani, Suresh, Eringathodi, Palaniandavar, Mallayan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9034113/
https://www.ncbi.nlm.nih.gov/pubmed/35478792
http://dx.doi.org/10.1039/d1ra03135j