An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties

Two new copper(ii) complexes [Cu(2)(L)(2)(OAc)(2)(H(2)O)(2)] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL(2)] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coord...

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Detalles Bibliográficos
Autores principales: Petrenko, Yuliia P., Piasta, Karolina, Khomenko, Dmytro M., Doroshchuk, Roman O., Shova, Sergiu, Novitchi, Ghénadie, Toporivska, Yuliya, Gumienna-Kontecka, Elzbieta, Martins, Luísa M. D. R. S., Lampeka, Rostyslav D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036593/
https://www.ncbi.nlm.nih.gov/pubmed/35479774
http://dx.doi.org/10.1039/d1ra03107d
Descripción
Sumario:Two new copper(ii) complexes [Cu(2)(L)(2)(OAc)(2)(H(2)O)(2)] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL(2)] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling.

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