An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties

Two new copper(ii) complexes [Cu(2)(L)(2)(OAc)(2)(H(2)O)(2)] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL(2)] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coord...

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Autores principales: Petrenko, Yuliia P., Piasta, Karolina, Khomenko, Dmytro M., Doroshchuk, Roman O., Shova, Sergiu, Novitchi, Ghénadie, Toporivska, Yuliya, Gumienna-Kontecka, Elzbieta, Martins, Luísa M. D. R. S., Lampeka, Rostyslav D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036593/
https://www.ncbi.nlm.nih.gov/pubmed/35479774
http://dx.doi.org/10.1039/d1ra03107d
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author Petrenko, Yuliia P.
Piasta, Karolina
Khomenko, Dmytro M.
Doroshchuk, Roman O.
Shova, Sergiu
Novitchi, Ghénadie
Toporivska, Yuliya
Gumienna-Kontecka, Elzbieta
Martins, Luísa M. D. R. S.
Lampeka, Rostyslav D.
author_facet Petrenko, Yuliia P.
Piasta, Karolina
Khomenko, Dmytro M.
Doroshchuk, Roman O.
Shova, Sergiu
Novitchi, Ghénadie
Toporivska, Yuliya
Gumienna-Kontecka, Elzbieta
Martins, Luísa M. D. R. S.
Lampeka, Rostyslav D.
author_sort Petrenko, Yuliia P.
collection PubMed
description Two new copper(ii) complexes [Cu(2)(L)(2)(OAc)(2)(H(2)O)(2)] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL(2)] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling.
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spelling pubmed-90365932022-04-26 An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties Petrenko, Yuliia P. Piasta, Karolina Khomenko, Dmytro M. Doroshchuk, Roman O. Shova, Sergiu Novitchi, Ghénadie Toporivska, Yuliya Gumienna-Kontecka, Elzbieta Martins, Luísa M. D. R. S. Lampeka, Rostyslav D. RSC Adv Chemistry Two new copper(ii) complexes [Cu(2)(L)(2)(OAc)(2)(H(2)O)(2)] (1) (L = 3-methyl-5-pyridin-2-yl-1,2,4-triazole) and [CuL(2)] (2) were prerared and thoroughly studied. The complexes are able to selectively catalyze the oxidation of styrene towards benzaldehyde and of cyclohexane to KA oil. The 2D coordination polymer 1 showed an antiferromagnetic behaviour attributed to the intrachain magnetic coupling. The Royal Society of Chemistry 2021-07-02 /pmc/articles/PMC9036593/ /pubmed/35479774 http://dx.doi.org/10.1039/d1ra03107d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Petrenko, Yuliia P.
Piasta, Karolina
Khomenko, Dmytro M.
Doroshchuk, Roman O.
Shova, Sergiu
Novitchi, Ghénadie
Toporivska, Yuliya
Gumienna-Kontecka, Elzbieta
Martins, Luísa M. D. R. S.
Lampeka, Rostyslav D.
An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
title An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
title_full An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
title_fullStr An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
title_full_unstemmed An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
title_short An investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
title_sort investigation of two copper(ii) complexes with a triazole derivative as a ligand: magnetic and catalytic properties
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036593/
https://www.ncbi.nlm.nih.gov/pubmed/35479774
http://dx.doi.org/10.1039/d1ra03107d
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