Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)

New branched polymerisations offer previously inaccessible macromolecules and architectural understanding is important as it provides insight into the branching mechanism and enables the determination of structure–property relationships. Here we present a detailed inverse gated (13)C NMR characteris...

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Detalles Bibliográficos
Autores principales: Cassin, Savannah R., Flynn, Sean, Chambon, Pierre, Rannard, Steve P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036642/
https://www.ncbi.nlm.nih.gov/pubmed/35479039
http://dx.doi.org/10.1039/d1ra03886a
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author Cassin, Savannah R.
Flynn, Sean
Chambon, Pierre
Rannard, Steve P.
author_facet Cassin, Savannah R.
Flynn, Sean
Chambon, Pierre
Rannard, Steve P.
author_sort Cassin, Savannah R.
collection PubMed
description New branched polymerisations offer previously inaccessible macromolecules and architectural understanding is important as it provides insight into the branching mechanism and enables the determination of structure–property relationships. Here we present a detailed inverse gated (13)C NMR characterisation of materials derived from the very recently reported Transfer-dominated Branching Radical Telomerisation (TBRT) approach to quantify branching and provide an insight into cyclisation.
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spelling pubmed-90366422022-04-26 Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT) Cassin, Savannah R. Flynn, Sean Chambon, Pierre Rannard, Steve P. RSC Adv Chemistry New branched polymerisations offer previously inaccessible macromolecules and architectural understanding is important as it provides insight into the branching mechanism and enables the determination of structure–property relationships. Here we present a detailed inverse gated (13)C NMR characterisation of materials derived from the very recently reported Transfer-dominated Branching Radical Telomerisation (TBRT) approach to quantify branching and provide an insight into cyclisation. The Royal Society of Chemistry 2021-07-12 /pmc/articles/PMC9036642/ /pubmed/35479039 http://dx.doi.org/10.1039/d1ra03886a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Cassin, Savannah R.
Flynn, Sean
Chambon, Pierre
Rannard, Steve P.
Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)
title Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)
title_full Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)
title_fullStr Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)
title_full_unstemmed Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)
title_short Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)
title_sort quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (tbrt)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036642/
https://www.ncbi.nlm.nih.gov/pubmed/35479039
http://dx.doi.org/10.1039/d1ra03886a
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