Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative

A trefoil-shaped salicylaldehyde azine derivative bearing multiple acidic protons displays base-induced multi-state luminescence. The azine was prepared through the reaction of 1,3,5-triformylphloroglucinol with 4-methoxysalicylaldehyde hydrazone. (1)H NMR spectroscopy revealed that the azine existe...

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Autores principales: Taniguchi, Noriho, Naito, Masaya, Miyagawa, Shinobu, Tokunaga, Yuji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036653/
https://www.ncbi.nlm.nih.gov/pubmed/35479037
http://dx.doi.org/10.1039/d1ra02627e
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author Taniguchi, Noriho
Naito, Masaya
Miyagawa, Shinobu
Tokunaga, Yuji
author_facet Taniguchi, Noriho
Naito, Masaya
Miyagawa, Shinobu
Tokunaga, Yuji
author_sort Taniguchi, Noriho
collection PubMed
description A trefoil-shaped salicylaldehyde azine derivative bearing multiple acidic protons displays base-induced multi-state luminescence. The azine was prepared through the reaction of 1,3,5-triformylphloroglucinol with 4-methoxysalicylaldehyde hydrazone. (1)H NMR spectroscopy revealed that the azine existed in solution at room temperature as an equilibrium mixture of two geometric isomers. The three-step deprotonation (four-state change) of the azine in solution was confirmed using (1)H NMR, UV-vis absorption, and emission spectroscopy.
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spelling pubmed-90366532022-04-26 Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative Taniguchi, Noriho Naito, Masaya Miyagawa, Shinobu Tokunaga, Yuji RSC Adv Chemistry A trefoil-shaped salicylaldehyde azine derivative bearing multiple acidic protons displays base-induced multi-state luminescence. The azine was prepared through the reaction of 1,3,5-triformylphloroglucinol with 4-methoxysalicylaldehyde hydrazone. (1)H NMR spectroscopy revealed that the azine existed in solution at room temperature as an equilibrium mixture of two geometric isomers. The three-step deprotonation (four-state change) of the azine in solution was confirmed using (1)H NMR, UV-vis absorption, and emission spectroscopy. The Royal Society of Chemistry 2021-07-07 /pmc/articles/PMC9036653/ /pubmed/35479037 http://dx.doi.org/10.1039/d1ra02627e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Taniguchi, Noriho
Naito, Masaya
Miyagawa, Shinobu
Tokunaga, Yuji
Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
title Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
title_full Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
title_fullStr Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
title_full_unstemmed Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
title_short Base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
title_sort base-induced multi-state fluorescence of a trefoil-shaped salicylaldehyde azine derivative
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036653/
https://www.ncbi.nlm.nih.gov/pubmed/35479037
http://dx.doi.org/10.1039/d1ra02627e
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AT miyagawashinobu baseinducedmultistatefluorescenceofatrefoilshapedsalicylaldehydeazinederivative
AT tokunagayuji baseinducedmultistatefluorescenceofatrefoilshapedsalicylaldehydeazinederivative

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