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Ho(2)Pd(1.3)Ge(2.7) – a ternary AlB(2)-type cluster glass system

We report a successful synthesis of a ternary AlB(2)-type intermetallic compound. The phase purity was obtained by fine-tuning the Pd : Ge ratio out of the idealized 1 : 3. Attempts to synthesize an Er analogue were not successful. We discuss the instability of the Er analogue based on the atomic si...

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Detalles Bibliográficos
Autores principales: Litzbarski, Leszek S., Klimczuk, Tomasz, Winiarski, Michał J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036949/
https://www.ncbi.nlm.nih.gov/pubmed/35478914
http://dx.doi.org/10.1039/d1ra04422b
Descripción
Sumario:We report a successful synthesis of a ternary AlB(2)-type intermetallic compound. The phase purity was obtained by fine-tuning the Pd : Ge ratio out of the idealized 1 : 3. Attempts to synthesize an Er analogue were not successful. We discuss the instability of the Er analogue based on the atomic size ratio and also suggest that the increased stability of Ho(2)Pd(1+x)Ge(3−x) in the Pd-rich range likely stems from a combination of atomic size ratio, electronic, and entropic factors. The new Ho(2)Pd(1.3)Ge(2.7) compound is found to exhibit cluster glass behavior with a freezing temperature of T ≈ 2.3 K.