Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media

Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF(3)-substituted phenonium ions can be generated to furnish original CF(3)-sub...

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Detalles Bibliográficos
Autores principales: Fernandes, Anthony J., Michelet, Bastien, Panossian, Armen, Martin-Mingot, Agnès, Leroux, Frédéric R., Thibaudeau, Sébastien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036966/
https://www.ncbi.nlm.nih.gov/pubmed/35478903
http://dx.doi.org/10.1039/d1ra04901a
Descripción
Sumario:Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF(3)-substituted phenonium ions can be generated to furnish original CF(3)-substituted dihydrostilbenes of interest.

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