Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media

Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF(3)-substituted phenonium ions can be generated to furnish original CF(3)-sub...

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Autores principales: Fernandes, Anthony J., Michelet, Bastien, Panossian, Armen, Martin-Mingot, Agnès, Leroux, Frédéric R., Thibaudeau, Sébastien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036966/
https://www.ncbi.nlm.nih.gov/pubmed/35478903
http://dx.doi.org/10.1039/d1ra04901a
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author Fernandes, Anthony J.
Michelet, Bastien
Panossian, Armen
Martin-Mingot, Agnès
Leroux, Frédéric R.
Thibaudeau, Sébastien
author_facet Fernandes, Anthony J.
Michelet, Bastien
Panossian, Armen
Martin-Mingot, Agnès
Leroux, Frédéric R.
Thibaudeau, Sébastien
author_sort Fernandes, Anthony J.
collection PubMed
description Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF(3)-substituted phenonium ions can be generated to furnish original CF(3)-substituted dihydrostilbenes of interest.
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spelling pubmed-90369662022-04-26 Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media Fernandes, Anthony J. Michelet, Bastien Panossian, Armen Martin-Mingot, Agnès Leroux, Frédéric R. Thibaudeau, Sébastien RSC Adv Chemistry Predestined to be transient theoretical species, phenonium ions can now be considered as cationic intermediates of choice in organic synthesis. Here, we demonstrate that under non-nucleophilic and superacidic conditions, CF(3)-substituted phenonium ions can be generated to furnish original CF(3)-substituted dihydrostilbenes of interest. The Royal Society of Chemistry 2021-07-26 /pmc/articles/PMC9036966/ /pubmed/35478903 http://dx.doi.org/10.1039/d1ra04901a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Fernandes, Anthony J.
Michelet, Bastien
Panossian, Armen
Martin-Mingot, Agnès
Leroux, Frédéric R.
Thibaudeau, Sébastien
Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
title Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
title_full Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
title_fullStr Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
title_full_unstemmed Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
title_short Formation of synthetically relevant CF(3)-substituted phenonium ions in superacid media
title_sort formation of synthetically relevant cf(3)-substituted phenonium ions in superacid media
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9036966/
https://www.ncbi.nlm.nih.gov/pubmed/35478903
http://dx.doi.org/10.1039/d1ra04901a
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