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Fast conversion of lithium (poly)sulfides in lithium–sulfur batteries using three-dimensional porous carbon

The slow redox kinetics of polysulfide hinders the rapid and complete conversion between soluble polysulfides and Li(2)S(2)/Li(2)S, resulting in unsatisfactory rate and cycle performance in lithium-sulfur batteries. Electrochemical catalysis, one effective method, promotes the reaction kinetics and...

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Detalles Bibliográficos
Autores principales: Liang, Xinghua, Wu, Xi, Zeng, Shuaibo, Xu, Wei, Jiang, Xingtao, Lan, Lingxiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037002/
https://www.ncbi.nlm.nih.gov/pubmed/35478876
http://dx.doi.org/10.1039/d1ra02704b
Descripción
Sumario:The slow redox kinetics of polysulfide hinders the rapid and complete conversion between soluble polysulfides and Li(2)S(2)/Li(2)S, resulting in unsatisfactory rate and cycle performance in lithium-sulfur batteries. Electrochemical catalysis, one effective method, promotes the reaction kinetics and inhibits the “shuttle effect”. Here, we present a three-dimensional ordered macro-porous carbon with abundant cobalt–nitrogen–carbon active sites as a matrix catalyst, leading to accelerated polysulfide redox kinetics. In addition, the interconnected conductive frameworks with ordered macro-porous carbon afford fast ion/electron transport and provide sufficient space to adapt to the volume expansion of the sulfur electrode. Owing to the aforementioned advantages, a lithium–sulfur battery with the matrix catalyst delivers a high specific capacity (1140 mA h g(−1) at 0.1C) and a low capacity decay rate (0.0937% per cycle over 500 cycles). Moreover, there is a high rate capacity (349.1 mA h g(−1)) even at the high current density of 2C and sulfur loading of 3.8 mg cm(−2) due to the improved polysulfide redox kinetics by a catalytic effect.