Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids

We report herein a cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement. This operationally simple protocol utilizes inexpensive CeCl(3) as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoate...

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Autores principales: Tripathy, Alisha Rani, Yedase, Girish Suresh, Yatham, Veera Reddy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037003/
https://www.ncbi.nlm.nih.gov/pubmed/35478894
http://dx.doi.org/10.1039/d1ra04130d
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author Tripathy, Alisha Rani
Yedase, Girish Suresh
Yatham, Veera Reddy
author_facet Tripathy, Alisha Rani
Yedase, Girish Suresh
Yatham, Veera Reddy
author_sort Tripathy, Alisha Rani
collection PubMed
description We report herein a cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement. This operationally simple protocol utilizes inexpensive CeCl(3) as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoates in good yields.
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spelling pubmed-90370032022-04-26 Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids Tripathy, Alisha Rani Yedase, Girish Suresh Yatham, Veera Reddy RSC Adv Chemistry We report herein a cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement. This operationally simple protocol utilizes inexpensive CeCl(3) as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoates in good yields. The Royal Society of Chemistry 2021-07-21 /pmc/articles/PMC9037003/ /pubmed/35478894 http://dx.doi.org/10.1039/d1ra04130d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Tripathy, Alisha Rani
Yedase, Girish Suresh
Yatham, Veera Reddy
Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
title Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
title_full Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
title_fullStr Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
title_full_unstemmed Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
title_short Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
title_sort cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037003/
https://www.ncbi.nlm.nih.gov/pubmed/35478894
http://dx.doi.org/10.1039/d1ra04130d
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AT yedasegirishsuresh ceriumphotocatalyzedradicalsmilesrearrangementof2aryloxybenzoicacids
AT yathamveerareddy ceriumphotocatalyzedradicalsmilesrearrangementof2aryloxybenzoicacids

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