Cargando…

Cerium photocatalyzed radical smiles rearrangement of 2-aryloxybenzoic acids

We report herein a cerium photocatalyzed aryl migration from an aryl ether to a carboxylic acid group through radical-Smiles rearrangement. This operationally simple protocol utilizes inexpensive CeCl(3) as a photocatalyst and converted a variety of 2-aryloxybenzoic acids into aryl-2-hydroxybenzoate...

Descripción completa

Detalles Bibliográficos
Autores principales:	Tripathy, Alisha Rani, Yedase, Girish Suresh, Yatham, Veera Reddy
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9037003/ https://www.ncbi.nlm.nih.gov/pubmed/35478894 http://dx.doi.org/10.1039/d1ra04130d

Ejemplares similares

Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones
por: Yedase, Girish Suresh, et al.
Publicado: (2021)

Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
por: Yatham, Veera Reddy, et al.
Publicado: (2019)

Radical Smiles Rearrangement: An Update
por: Allart-Simon, Ingrid, et al.
Publicado: (2016)

PPh(3)/NaI driven photocatalytic decarboxylative radical cascade alkylarylation reaction of 2-isocyanobiaryls
por: Wadekar, Ketan, et al.
Publicado: (2020)

Photocatalyzed Dowd–Beckwith radical-polar crossover reaction for the synthesis of medium-sized carbocyclic compounds
por: Singha, Tushar, et al.
Publicado: (2023)

Kinetics of Photocatalyzed Reactions: Five Lessons Learned
por: Ollis, David F.
Publicado: (2018)

Antioxidant activity of cerium dioxide nanoparticles and nanorods in scavenging hydroxyl radicals
por: Filippi, Alexander, et al.
Publicado: (2019)

Modular synthesis of α-arylated carboxylic acids, esters and amides via photocatalyzed triple C–F bond cleavage of methyltrifluorides
por: Li, Sifan, et al.
Publicado: (2022)

Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
por: Chen, Fengjuan, et al.
Publicado: (2021)

Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates
por: Yatham, Veera Reddy, et al.
Publicado: (2015)

Penta-fluorophenol: a Smiles rearrangement-inspired cysteine-selective fluorescent probe for imaging of human glioblastoma
por: An, Jong Min, et al.
Publicado: (2020)

Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors
por: Jorea, Alexandra, et al.
Publicado: (2022)

Copper‐Photocatalyzed Hydroboration of Alkynes and Alkenes
por: Zhong, Mingbing, et al.
Publicado: (2021)

Diarylamine Synthesis via Desulfinylative Smiles Rearrangement
por: Sephton, Thomas, et al.
Publicado: (2022)

Carbon nitride photocatalyzes regioselective aminium radical addition to the carbonyl bond and yields N-fused pyrroles
por: Kurpil, Bogdan, et al.
Publicado: (2019)

Eradicating mass spectrometric glycan rearrangement by utilizing free radicals
por: Desai, Nikunj, et al.
Publicado: (2016)

Synthesis of Various 2-Aminobenzoxazoles: The Study of Cyclization and Smiles Rearrangement
por: Šlachtová, Veronika, et al.
Publicado: (2019)

Photocatalyzed syntheses of phenanthrenes and their aza-analogues. A review
por: Del Tito, Alessandra, et al.
Publicado: (2020)

Optochemical Control of Therapeutic Agents through Photocatalyzed Isomerization
por: Watson, Emma E., et al.
Publicado: (2022)

N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes
por: Allen, Laura J., et al.
Publicado: (2014)

A smile is all you need: predicting limiting activity coefficients from SMILES with natural language processing
por: Winter, Benedikt, et al.
Publicado: (2022)

An NHC-Catalyzed Desulfonylative Smiles Rearrangement of Pyrrole and Indole Carboxaldehydes
por: Swaby, Caitlin, et al.
Publicado: (2023)

Regio- and Diastereoselective Intermolecular [2+2] Cycloadditions Photocatalyzed by Quantum Dots
por: Jiang, Yishu, et al.
Publicado: (2019)

Accessing chiral sulfones bearing quaternary carbon stereocenters via photoinduced radical sulfur dioxide insertion and Truce–Smiles rearrangement
por: Huang, Jiapian, et al.
Publicado: (2022)

Correction: A smile is all you need: predicting limiting activity coefficients from SMILES with natural language processing
por: Winter, Benedikt, et al.
Publicado: (2022)

Hydrogenations without Hydrogen: Titania Photocatalyzed Reductions of Maleimides and Aldehydes
por: Manley, David W., et al.
Publicado: (2014)

Photocatalyzed synthesis of isochromanones and isobenzofuranones under batch and flow conditions
por: Anselmo, Manuel, et al.
Publicado: (2017)

Photocatalyzed regioselective hydrosilylation for the divergent synthesis of geminal and vicinal borosilanes
por: Kong, Degong, et al.
Publicado: (2023)

Visible-Light-Photocatalyzed Reductions of N-Heterocyclic Nitroaryls to Anilines Utilizing Ascorbic Acid Reductant
por: Todorov, Aleksandar R., et al.
Publicado: (2019)

A bifunctional cerium phosphate catalyst for chemoselective acetalization
por: Kanai, Shunsuke, et al.
Publicado: (2017)

Cerium oxide nanoparticles: properties, biosynthesis and biomedical application
por: Singh, Kshitij RB, et al.
Publicado: (2020)

Advanced applications of cerium oxide based nanozymes in cancer
por: Feng, Na, et al.
Publicado: (2022)

Cerium–quinone redox couples put under scrutiny
por: Bayer, Uwe, et al.
Publicado: (2020)

Triarylmethanes and their Medium‐Ring Analogues by Unactivated Truce–Smiles Rearrangement of Benzanilides
por: Abrams, Roman, et al.
Publicado: (2021)

Cerium oxide (CeO2)
por: Scire, Salvatore, et al.
Publicado: (2019)

A new and efficient lactic acid polymerization by multimetallic cerium complexes: a poly(lactic acid) suitable for biomedical applications
por: Pastore, Genny, et al.
Publicado: (2021)

Thermal rearrangement of tert-butylsulfinamide
por: Arava, Veera Reddy, et al.
Publicado: (2011)

Synthesis of Polysubstituted Pyridines and Pyrazines via Truce–Smiles Rearrangement of Amino Acid-Based 4-Nitrobenzenesulfonamides
por: Tkadlecová, Michaela, et al.
Publicado: (2023)

Photocatalyzed Transition‐Metal‐Free Oxidative Cross‐Coupling Reactions of Tetraorganoborates
por: Music, Arif, et al.
Publicado: (2021)

Efficient access to aliphatic esters by photocatalyzed alkoxycarbonylation of alkenes with alkyloxalyl chlorides
por: Chen, Jian-Qiang, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_tifvk6av6psbgeat54b8q5bqnb