Cargando…

H(2) activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

Hydrogen is a clean fuel alternative to fossil fuels, and it is vital to develop catalysts for its efficient activation and production. We investigate the reaction mechanism of H(2) activation in an aqueous solution by the recently developed NiFe complex (Ogo et al. Sci. Adv. 2020, 6, eaaz8181) usin...

Descripción completa

Detalles Bibliográficos
Autores principales:	Isegawa, Miho, Matsumoto, Takahiro, Ogo, Seiji
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9038005/ https://www.ncbi.nlm.nih.gov/pubmed/35480737 http://dx.doi.org/10.1039/d1ra05928a

Ejemplares similares

[NiFe], [FeFe], and [Fe] hydrogenase models from isomers
por: Ogo, Seiji, et al.
Publicado: (2020)

Geometrical influence on the non-biomimetic heterolytic splitting of H(2) by bio-inspired [FeFe]-hydrogenase complexes: a rare example of inverted frustrated Lewis pair based reactivity
por: Chatelain, Lucile, et al.
Publicado: (2022)

Heterolytic Si−H Bond Cleavage at a Molybdenum‐Oxido‐Based Lewis Pair
por: Zwettler, Niklas, et al.
Publicado: (2018)

Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept
por: Skara, Gabriella, et al.
Publicado: (2017)

Heterolytic bond activation at gold: evidence for gold(iii) H–B, H–Si complexes, H–H and H–C cleavage
por: Rocchigiani, Luca, et al.
Publicado: (2019)

Protein Film Infrared Electrochemistry Demonstrated for Study of H(2) Oxidation by a [NiFe] Hydrogenase
por: Ash, Philip A., et al.
Publicado: (2017)

Minimal Influence of [NiFe] Hydrogenase on Hydrogen Isotope Fractionation in H(2)-Oxidizing Cupriavidus necator
por: Campbell, Brian J., et al.
Publicado: (2017)

Discovery of Dark pH-Dependent H(+) Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate
por: Murphy, Bonnie J., et al.
Publicado: (2015)

The large subunit of the regulatory [NiFe]-hydrogenase from Ralstonia eutropha – a minimal hydrogenase?
por: Caserta, Giorgio, et al.
Publicado: (2020)

Electrochemical insights into the mechanism of NiFe membrane-bound hydrogenases
por: Flanagan, Lindsey A., et al.
Publicado: (2016)

Optimization of Culture Conditions for Oxygen-Tolerant Regulatory [NiFe]-Hydrogenase Production from Ralstonia eutropha H16 in Escherichia coli
por: Fan, Qin, et al.
Publicado: (2021)

Studying O(2) pathways in [NiFe]- and [NiFeSe]-hydrogenases
por: Barbosa, Tiago M., et al.
Publicado: (2020)

Activation of a [NiFe]-hydrogenase-4 isoenzyme by maturation proteases
por: Finney, Alexander J., et al.
Publicado: (2020)

Structure and electron transfer pathways of an electron-bifurcating NiFe-hydrogenase
por: Feng, Xiang, et al.
Publicado: (2022)

Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H(2) Oxidation by a NiFe Hydrogenase**
por: Hidalgo, Ricardo, et al.
Publicado: (2015)

Interaction between Hydrogenase Maturation Factors HypA and HypB Is Required for [NiFe]-Hydrogenase Maturation
por: Chan, Kwok-Ho, et al.
Publicado: (2012)

Re-engineering a NiFe hydrogenase to increase the H(2) production bias while maintaining native levels of O(2) tolerance
por: Flanagan, Lindsey A., et al.
Publicado: (2016)

The thermoacidophilic methanotroph Methylacidiphilum fumariolicum SolV oxidizes subatmospheric H(2) with a high-affinity, membrane-associated [NiFe] hydrogenase
por: Schmitz, Rob A., et al.
Publicado: (2020)

Metal–ligand multiple bonds as frustrated Lewis pairs for C–H functionalization
por: Whited, Matthew T
Publicado: (2012)

Direct cyanidation of silver sulfide by heterolytic C–CN bond cleavage of acetonitrile
por: Das, Biraj, et al.
Publicado: (2020)

Production of biohydrogen by recombinant expression of [NiFe]-hydrogenase 1 in Escherichia coli
por: Kim, Jaoon YH, et al.
Publicado: (2010)

Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy
por: Ogata, Hideaki, et al.
Publicado: (2015)

How the oxygen tolerance of a [NiFe]-hydrogenase depends on quaternary structure
por: Wulff, Philip, et al.
Publicado: (2016)

Dual role of HupF in the biosynthesis of [NiFe] hydrogenase in Rhizobium leguminosarum
por: Albareda, Marta, et al.
Publicado: (2012)

Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites
por: Yang, Xuemei, et al.
Publicado: (2018)

The exchange activities of [Fe] hydrogenase (iron–sulfur-cluster-free hydrogenase) from methanogenic archaea in comparison with the exchange activities of [FeFe] and [NiFe] hydrogenases
por: Vogt, Sonja, et al.
Publicado: (2007)

Multifaceted SlyD from Helicobacter pylori: implication in [NiFe] hydrogenase maturation
por: Cheng, Tianfan, et al.
Publicado: (2011)

Heterologous Expression of Alteromonas macleodii and Thiocapsa roseopersicina [NiFe] Hydrogenases in Synechococcus elongatus
por: Weyman, Philip D., et al.
Publicado: (2011)

How the structure of the large subunit controls function in an oxygen-tolerant [NiFe]-hydrogenase
por: Bowman, Lisa, et al.
Publicado: (2014)

Designed Surface Residue Substitutions in [NiFe] Hydrogenase that Improve Electron Transfer Characteristics
por: Yonemoto, Isaac T., et al.
Publicado: (2015)

Distal [FeS]-Cluster Coordination in [NiFe]-Hydrogenase Facilitates Intermolecular Electron Transfer
por: Petrenko, Alexander, et al.
Publicado: (2017)

What is the trigger mechanism for the reversal of electron flow in oxygen-tolerant [NiFe] hydrogenases?
por: Dance, Ian
Publicado: (2015)

[NiFe]-hydrogenases are constitutively expressed in an enriched Methanobacterium sp. population during electromethanogenesis
por: Perona-Vico, Elisabet, et al.
Publicado: (2019)

Proton Transfer in the Catalytic Cycle of [NiFe] Hydrogenases: Insight from Vibrational Spectroscopy
por: Ash, Philip A., et al.
Publicado: (2017)

Structural characterization of HypX responsible for CO biosynthesis in the maturation of NiFe-hydrogenase
por: Muraki, Norifumi, et al.
Publicado: (2019)

Modeling of the Electrostatic Interaction and Catalytic Activity of [NiFe] Hydrogenases on a Planar Electrode
por: Ruiz-Rodríguez, Manuel Antonio, et al.
Publicado: (2022)

Developing high-affinity, oxygen-insensitive [NiFe]-hydrogenases as biocatalysts for energy conversion
por: Greening, Chris, et al.
Publicado: (2023)

Exchange of a Single Amino Acid Residue in the HybG Chaperone Allows Maturation of All H(2)-Activating [NiFe]-Hydrogenases in Escherichia coli
por: Haase, Alexander, et al.
Publicado: (2022)

Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation
por: Grundy, Matthew E., et al.
Publicado: (2023)

Characteristics of the Frustrated Lewis Pairs (FLPs) on the Surface of Albite and the Corresponding Mechanism of H(2) Activation
por: Zhou, Yannan, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_kgnscp4t0dgt7oriphu3j73dgh