Trimerization and cyclization of reactive P-functionalities confined within OCO pincers

In order to stabilize a 10–P–3 species with C(2v) symmetry and two lone pairs on the central phosphorus atom, a specialized ligand is required. Using an NCN pincer, previous efforts to enforce this planarized geometry at P resulted in the formation of a C(s)-symmetric, 10π-electron benzazaphosphole...

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Detalles Bibliográficos
Autores principales: Chinen, Beatrice L., Hyvl, Jakub, Brayton, Daniel F., Riek, Matthew M., Yoshida, Wesley Y., Chapp, Timothy W., Rheingold, Arnold L., Cain, Matthew F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9038090/
https://www.ncbi.nlm.nih.gov/pubmed/35478534
http://dx.doi.org/10.1039/d1ra05926b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9038090/
https://www.ncbi.nlm.nih.gov/pubmed/35478534
http://dx.doi.org/10.1039/d1ra05926b

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