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Trimerization and cyclization of reactive P-functionalities confined within OCO pincers
In order to stabilize a 10–P–3 species with C(2v) symmetry and two lone pairs on the central phosphorus atom, a specialized ligand is required. Using an NCN pincer, previous efforts to enforce this planarized geometry at P resulted in the formation of a C(s)-symmetric, 10π-electron benzazaphosphole...
Autores principales: | Chinen, Beatrice L., Hyvl, Jakub, Brayton, Daniel F., Riek, Matthew M., Yoshida, Wesley Y., Chapp, Timothy W., Rheingold, Arnold L., Cain, Matthew F. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9038090/ https://www.ncbi.nlm.nih.gov/pubmed/35478534 http://dx.doi.org/10.1039/d1ra05926b |
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