Cargando…

Domino C–C/C–O bond formation: palladium-catalyzed regioselective synthesis of 7-iodobenzo[b]furans using 1,2,3-triiodobenzenes and benzylketones

A facile and efficient synthesis of 7-iodobenzo[b]furan derivatives via a highly regioselective tandem α-arylation/intramolecular O-arylation of 5-substituted-1,2,3-triiodobenzenes and benzylketones is described. Remarkably, the α-arylation coupling reactions initiate exclusively at the least steric...

Descripción completa

Detalles Bibliográficos
Autores principales:	Al-Zoubi, Raed M., Al-Jammal, Walid K., Ferguson, Michael J., Murphy, Graham K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9040925/ https://www.ncbi.nlm.nih.gov/pubmed/35493993 http://dx.doi.org/10.1039/d1ra05730h

Ejemplares similares

Palladium-catalyzed highly regioselective mono and double Sonogashira cross-coupling reactions of 5-substituted-1,2,3-triiodobenzene under ambient conditions
por: Al-Zoubi, Raed M., et al.
Publicado: (2020)

Palladium-Catalyzed C–H Arylation of 1,2,3-Triazoles
por: Zhang, Chengwei, et al.
Publicado: (2016)

Palladium-Catalyzed Oxidative Domino Carbocyclization–Arylation of Bisallenes
por: Volla, Chandra M. R., et al.
Publicado: (2016)

Palladium-Catalyzed Regioselective Arylation of Unprotected Allylamines
por: Landge, Vinod G., et al.
Publicado: (2020)

Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids
por: Li, Luan-Ying, et al.
Publicado: (2022)

Total Synthesis of Cyclopiamide A Using Palladium-Catalyzed Domino Cyclization
por: Park, Sunhwa, et al.
Publicado: (2020)

Palladium-Catalyzed Domino Aminocarbonylation of Alkynols: Direct and Selective Synthesis of Itaconimides
por: Ge, Yao, et al.
Publicado: (2021)

Synthesis of Heteroannulated Indolopyrazines through Domino N–H Palladium-Catalyzed/Metal-Free Oxidative C–H Bond Activation
por: Kvashnin, Yuriy A., et al.
Publicado: (2020)

Regioselective Pd-catalyzed α-alkylation of furans using alkyl iodides
por: Yuan, Jiaqi, et al.
Publicado: (2021)

Enantio‐ and Regioselective Palladium(II)‐Catalyzed Dioxygenation of (Aza‐)Alkenols
por: Giofrè, Sabrina, et al.
Publicado: (2021)

A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes
por: Fu, Wai Chung, et al.
Publicado: (2019)

Controlling Regioselectivity in Palladium‐Catalyzed C−H Activation/Aryl–Aryl Coupling of 4‐Phenylamino[2.2]paracyclophane
por: Zippel, Christoph, et al.
Publicado: (2020)

A regioselective C7 bromination and C7 palladium-catalyzed Suzuki–Miyaura cross-coupling arylation of 4-substituted NH-free indazoles
por: Boujdi, Khalid, et al.
Publicado: (2021)

Regioselective Gold-Catalyzed Oxidative C–N Bond Formation
por: Marchetti, Louis, et al.
Publicado: (2014)

Synthesis of benzoxazoles via an iron-catalyzed domino C–N/C–O cross-coupling reaction
por: Yang, Bo, et al.
Publicado: (2018)

Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp(2) C—H Bonds of N-Aryl-2-amino Pyridine Derivatives
por: Koley, Moumita, et al.
Publicado: (2012)

Cyclopropylammonium 4-iodobenzoate
por: Lemmerer, Andreas
Publicado: (2012)

Ligand-free iridium-catalyzed regioselective C–H borylation of indoles
por: Pan, Zilong, et al.
Publicado: (2021)

Heterogeneously Catalyzed Domino Synthesis of 3-Indolylquinones Involving Direct Oxidative C–C Coupling of Hydroquinones and Indoles
por: Kamble, Sumit B., et al.
Publicado: (2017)

Regioselective synthesis of spirocyclic pyrrolines via a palladium-catalyzed Narasaka–Heck/C–H activation/[4 + 2] annulation cascade reaction
por: Wei, Wan-Xu, et al.
Publicado: (2022)

Palladium-Catalyzed Direct C=H Functionalization of Benzoquinone**
por: Walker, Sarah E, et al.
Publicado: (2014)

Ruthenium(ii)-catalyzed regioselective direct C4- and C5-diamidation of indoles and mechanistic studies
por: Devkota, Shreedhar, et al.
Publicado: (2021)

Palladium catalyzed regioselective B–C(sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes
por: Quan, Yangjian, et al.
Publicado: (2016)

Stereoretentive and regioselective selenium-catalyzed intermolecular propargylic C–H amination of alkynes
por: Maloney, T. Parker, et al.
Publicado: (2022)

Thioether-enabled palladium-catalyzed atroposelective C–H olefination for N–C and C–C axial chirality
por: Li, Yanjun, et al.
Publicado: (2022)

Palladium-Catalyzed Transannular C–H Functionalization of Alicyclic Amines
por: Topczewski, Joseph J., et al.
Publicado: (2016)

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
por: Ruiz-Castillo, Paula, et al.
Publicado: (2016)

Palladium-catalyzed dehydrogenative C–H cyclization for isoindolinone synthesis
por: Abe, Masahiro, et al.
Publicado: (2021)

Directed Palladium Catalyzed C−H (Ethoxycarbonyl)difluoromethylthiolation Reactions
por: Doche, Floriane, et al.
Publicado: (2022)

Selectivity Control in the Tandem Aromatization of Bio‐Based Furanics Catalyzed by Solid Acids and Palladium
por: Genuino, Homer C., et al.
Publicado: (2016)

Palladium-catalyzed cross-coupling reaction of alkenyl aluminums with 2-bromobenzo[b]furans
por: Wen, Chang, et al.
Publicado: (2020)

Regioselective palladium-catalyzed ring-opening reactions of C1-substituted oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylates
por: Edmunds, Michael, et al.
Publicado: (2016)

Palladium-Catalyzed Ortho C–H Arylation of Unprotected Anilines: Chemo- and Regioselectivity Enabled by the Cooperating Ligand [2,2′-Bipyridin]-6(1H)-one
por: Pinilla, Cintya, et al.
Publicado: (2022)

What the Heck?—Automated Regioselectivity Calculations of Palladium-Catalyzed Heck Reactions Using Quantum Chemistry
por: Ree, Nicolai, et al.
Publicado: (2022)

A novel and efficient synthesis of phenanthrene derivatives via palladium/norbornadiene-catalyzed domino one-pot reaction
por: Zhong, Yue, et al.
Publicado: (2019)

Recent Advances in the Synthesis of 3,n-Fused Tricyclic Indole Skeletons via Palladium-Catalyzed Domino Reactions
por: Fan, Liangxin, et al.
Publicado: (2023)

2-(Tritylsulfanyl)ethyl 2-iodobenzoate
por: Zhu, Xin, et al.
Publicado: (2011)

2-(Tritylsulfanyl)ethyl 3-iodobenzoate
por: Zhu, Xin, et al.
Publicado: (2011)

Palladium-catalyzed substitution of (coumarinyl)methyl acetates with C-, N-, and S-nucleophiles
por: Chattopadhyay, Kalicharan, et al.
Publicado: (2012)

Palladium Catalyzed Allylic C-H Alkylation: A Mechanistic Perspective
por: Engelin, Casper Junker, et al.
Publicado: (2011)

Cannot write session to /tmp/vufind_sessions/sess_pppu1kv0eg1lmt9s6o0evg37a6