Effect of flame retardants on mechanical and thermal properties of bio-based polyurethane rigid foams

A soy oil-based polyol (HSBP) was synthesized from epoxidized soy oil through a ring-opening reaction with distilled water. A phosphorus-containing flame retardant (DOPO–HSBP) was synthesized through the reaction of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and HSBP. A nitrogen-containing flame retardant (T–D) was prepared by the reaction of diethanolamine with glycol diglycidyl ether. The structures of HSBP, DOPO–HSBP, and T–D were characterized by Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance ((1)H NMR). The flame-retardant rigid polyurethane foam (PPUFs and NPUFs) was prepared successfully by mixing HSBP, DOPO–HSBP, and T–D. The effects of DOPO–HSBP content on the mechanical, thermal, and flame-retardant properties of PPUFs and NPUFs were investigated by tensile tests, thermogravimetric analyses (TGA), limiting oxygen index (LOI), and UL-94 vertical burning level. The morphology of PPUFs and NPUFs was studied via scanning electron microscopy (SEM). With the increase in the percentage of DOPO–HSBP added, the flame retardant property of rigid polyurethane foam (RPUF) was greatly improved. When the phosphorus-containing flame retardant DOPO–HSBP was added to 50% of the RPUF with the nitrogen-containing flame retardant T–D, the LOI value of the foam increased from 18.3 to 25.5, and the UL-94 result was classified as “V-0” with almost no effect on the mechanical properties of the RPUF. The results showed that the phosphorus and nitrogen synergistic flame retardants of DOPO–HSBP and T–D can endow excellent flame retardant properties to RPUF without affecting its mechanical properties.