Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion

Zeolite mordenite (MOR) is one of the most studied zeolites for the stepwise direct conversion of methane to methanol, but it also can exist in two forms: large port and small port. Here we report that the synthesis and selection of the parent mordenite is critical for optimizing productivity, and t...

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Detalles Bibliográficos
Autores principales: Knorpp, Amy J., Pinar, Ana B., Newton, Mark A., Li, Teng, Calbry-Muzyka, Adelaide, van Bokhoven, Jeroen A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041376/
https://www.ncbi.nlm.nih.gov/pubmed/35498933
http://dx.doi.org/10.1039/d1ra04643h
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author Knorpp, Amy J.
Pinar, Ana B.
Newton, Mark A.
Li, Teng
Calbry-Muzyka, Adelaide
van Bokhoven, Jeroen A.
author_facet Knorpp, Amy J.
Pinar, Ana B.
Newton, Mark A.
Li, Teng
Calbry-Muzyka, Adelaide
van Bokhoven, Jeroen A.
author_sort Knorpp, Amy J.
collection PubMed
description Zeolite mordenite (MOR) is one of the most studied zeolites for the stepwise direct conversion of methane to methanol, but it also can exist in two forms: large port and small port. Here we report that the synthesis and selection of the parent mordenite is critical for optimizing productivity, and that large-port mordenite outperforms small-port mordenite for the stepwise conversion of methane to methanol.
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spelling pubmed-90413762022-04-28 Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion Knorpp, Amy J. Pinar, Ana B. Newton, Mark A. Li, Teng Calbry-Muzyka, Adelaide van Bokhoven, Jeroen A. RSC Adv Chemistry Zeolite mordenite (MOR) is one of the most studied zeolites for the stepwise direct conversion of methane to methanol, but it also can exist in two forms: large port and small port. Here we report that the synthesis and selection of the parent mordenite is critical for optimizing productivity, and that large-port mordenite outperforms small-port mordenite for the stepwise conversion of methane to methanol. The Royal Society of Chemistry 2021-09-20 /pmc/articles/PMC9041376/ /pubmed/35498933 http://dx.doi.org/10.1039/d1ra04643h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Knorpp, Amy J.
Pinar, Ana B.
Newton, Mark A.
Li, Teng
Calbry-Muzyka, Adelaide
van Bokhoven, Jeroen A.
Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion
title Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion
title_full Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion
title_fullStr Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion
title_full_unstemmed Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion
title_short Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion
title_sort copper-exchanged large-port and small-port mordenite (mor) for methane-to-methanol conversion
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041376/
https://www.ncbi.nlm.nih.gov/pubmed/35498933
http://dx.doi.org/10.1039/d1ra04643h
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