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Synthesis of cyanooxovanadate and cyanosilylation of ketones
The cyanosilylation was performed by using metavanadate catalysts, and in situ measurements revealed the formation of [VO(2)(CN)(3)](2−) and [VO(4)TMS(2)](−) under reaction conditions. The reaction of [VO(2)(CN)(3)](2−), trimethylsilyl cyanide (TMSCN), and water afforded [VO(4)TMS(2)](−) and CN(−),...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041443/ https://www.ncbi.nlm.nih.gov/pubmed/35496882 http://dx.doi.org/10.1039/d1ra05879g |