Rapid kinetic evaluation of homogeneous single-site metallocene catalysts and cyclic diene: how do the catalytic activity, molecular weight, and diene incorporation rate of olefins affect each other?

The kinetics and mechanism of ethylene and cyclic diene 5-ethylidene-2-norbornene (ENB) copolymerization catalyzed by rac-Et(Ind)(2)ZrCl(2)/[Ph(3)C][B(C(6)F(5))(4)]/triisobutylaluminium (TIBA) were investigated using a quench-labeling procedure using 2-thiophenecarbonyl chloride (TPCC). The E/ENB co...

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Detalles Bibliográficos
Autores principales: Ali, Amjad, Nadeem, Muhammad, Lu, Jinwei, Moradian, Jamile Mohammadi, Rasheed, Tahir, Aziz, Tariq, Maouche, Chanez, Guo, Yintian, Awais, Muhammad, Zhiqiang, Fan, Quo, Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041555/
https://www.ncbi.nlm.nih.gov/pubmed/35496867
http://dx.doi.org/10.1039/d1ra06243c

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