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X-ray absorption spectroscopy of exemplary platinum porphyrin and corrole derivatives: metal- versus ligand-centered oxidation

A combination of Pt L(3)-edge X-ray absorption spectroscopy (EXAFS and XANES) and DFT (TPSS) calculations have been performed on powder samples of the archetypal platinum porphyrinoid complexes Pt(II)[TpCF(3)PP], Pt(IV)[TpCF(3)PP]Cl(2), and Pt(IV)[TpCF(3)PC](Ar)(py), where TpCF(3)PP(2−) = meso-tetra...

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Detalles Bibliográficos
Autores principales:	Matson, Benjamin D., Thomas, Kolle E., Alemayehu, Abraham B., Ghosh, Abhik, Sarangi, Ritimukta
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9041989/ https://www.ncbi.nlm.nih.gov/pubmed/35495496 http://dx.doi.org/10.1039/d1ra06151h

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