Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof

Lithium anions derived from O-carbonate-protected cyanohydrins undergo conjugate addition to cycloalkenones with the concomitant transfer of the alkoxycarbonyl group to produce tricarbonyl compounds. These products offer numerous possibilities for further elaboration. The synthetic potential of the...

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Detalles Bibliográficos
Autores principales: Madroñero, Diego, Mujica-Martinez, Cesar A., Vázquez, Alfredo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042245/
https://www.ncbi.nlm.nih.gov/pubmed/35497560
http://dx.doi.org/10.1039/d1ra05187c
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author Madroñero, Diego
Mujica-Martinez, Cesar A.
Vázquez, Alfredo
author_facet Madroñero, Diego
Mujica-Martinez, Cesar A.
Vázquez, Alfredo
author_sort Madroñero, Diego
collection PubMed
description Lithium anions derived from O-carbonate-protected cyanohydrins undergo conjugate addition to cycloalkenones with the concomitant transfer of the alkoxycarbonyl group to produce tricarbonyl compounds. These products offer numerous possibilities for further elaboration. The synthetic potential of the cascade products was demonstrated by forming bicyclic and tricyclic systems through intramolecular condensation reactions.
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spelling pubmed-90422452022-04-28 Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof Madroñero, Diego Mujica-Martinez, Cesar A. Vázquez, Alfredo RSC Adv Chemistry Lithium anions derived from O-carbonate-protected cyanohydrins undergo conjugate addition to cycloalkenones with the concomitant transfer of the alkoxycarbonyl group to produce tricarbonyl compounds. These products offer numerous possibilities for further elaboration. The synthetic potential of the cascade products was demonstrated by forming bicyclic and tricyclic systems through intramolecular condensation reactions. The Royal Society of Chemistry 2021-10-11 /pmc/articles/PMC9042245/ /pubmed/35497560 http://dx.doi.org/10.1039/d1ra05187c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Madroñero, Diego
Mujica-Martinez, Cesar A.
Vázquez, Alfredo
Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
title Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
title_full Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
title_fullStr Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
title_full_unstemmed Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
title_short Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
title_sort consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042245/
https://www.ncbi.nlm.nih.gov/pubmed/35497560
http://dx.doi.org/10.1039/d1ra05187c
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