Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system

An operationally rapid and efficient synthesis of N-sulfonyl formamidines that proceeds under mild conditions was achieved by reaction of a mixture of an amine, a sulfonyl azide, and a terminal ynone under catalyst-free and solvent-free conditions. Terminal ynones provide the C source to formamidine...

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Detalles Bibliográficos
Autores principales: Zhou, Zitong, Zhao, Yu, Zhou, Donghua, Li, Li, Luo, Hui, Cui, Liao, Yang, Weiguang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042323/
https://www.ncbi.nlm.nih.gov/pubmed/35497291
http://dx.doi.org/10.1039/d1ra06809a
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author Zhou, Zitong
Zhao, Yu
Zhou, Donghua
Li, Li
Luo, Hui
Cui, Liao
Yang, Weiguang
author_facet Zhou, Zitong
Zhao, Yu
Zhou, Donghua
Li, Li
Luo, Hui
Cui, Liao
Yang, Weiguang
author_sort Zhou, Zitong
collection PubMed
description An operationally rapid and efficient synthesis of N-sulfonyl formamidines that proceeds under mild conditions was achieved by reaction of a mixture of an amine, a sulfonyl azide, and a terminal ynone under catalyst-free and solvent-free conditions. Terminal ynones provide the C source to formamidines via complete cleavage of C[triple bond, length as m-dash]C.
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spelling pubmed-90423232022-04-28 Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system Zhou, Zitong Zhao, Yu Zhou, Donghua Li, Li Luo, Hui Cui, Liao Yang, Weiguang RSC Adv Chemistry An operationally rapid and efficient synthesis of N-sulfonyl formamidines that proceeds under mild conditions was achieved by reaction of a mixture of an amine, a sulfonyl azide, and a terminal ynone under catalyst-free and solvent-free conditions. Terminal ynones provide the C source to formamidines via complete cleavage of C[triple bond, length as m-dash]C. The Royal Society of Chemistry 2021-10-18 /pmc/articles/PMC9042323/ /pubmed/35497291 http://dx.doi.org/10.1039/d1ra06809a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhou, Zitong
Zhao, Yu
Zhou, Donghua
Li, Li
Luo, Hui
Cui, Liao
Yang, Weiguang
Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
title Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
title_full Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
title_fullStr Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
title_full_unstemmed Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
title_short Rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
title_sort rapid and efficient synthesis of formamidines in a catalyst-free and solvent-free system
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042323/
https://www.ncbi.nlm.nih.gov/pubmed/35497291
http://dx.doi.org/10.1039/d1ra06809a
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