A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes

An asymmetric bipy/NHC ligand L has been used to construct Au/Au, Au/Ag and Au/Cu bimetallic complexes through prior coordination of the NHC to Au(i) and subsequent introduction of the second group 11 metal ion at the bipy donor of the hybrid ligand. The complex [Au(κ(C)-L)(2)]BF(4,)1, has been used...

Descripción completa

Detalles Bibliográficos
Autores principales: Kariuki, Benson M., Platts, James A., Newman, Paul D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042343/
https://www.ncbi.nlm.nih.gov/pubmed/35497314
http://dx.doi.org/10.1039/d1ra06581e
_version_ 1784694644533100544
author Kariuki, Benson M.
Platts, James A.
Newman, Paul D.
author_facet Kariuki, Benson M.
Platts, James A.
Newman, Paul D.
author_sort Kariuki, Benson M.
collection PubMed
description An asymmetric bipy/NHC ligand L has been used to construct Au/Au, Au/Ag and Au/Cu bimetallic complexes through prior coordination of the NHC to Au(i) and subsequent introduction of the second group 11 metal ion at the bipy donor of the hybrid ligand. The complex [Au(κ(C)-L)(2)]BF(4,)1, has been used as the precursor for the formation of [AuAg(κ-C(Au),κ(2)-N,N′(Ag)-1)(2)](BF(4))(2), 2a, [AuCu(κ-C(Au),κ(2)-N,N′(Cu)-1)(2)](BF(4))(2), 2b and [AuAu′(κ-C(Au/Au′),κ(1)-N(Au/Au′)-1)(2)](BF(4))(2), 3.
format Online
Article
Text
id pubmed-9042343
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90423432022-04-28 A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes Kariuki, Benson M. Platts, James A. Newman, Paul D. RSC Adv Chemistry An asymmetric bipy/NHC ligand L has been used to construct Au/Au, Au/Ag and Au/Cu bimetallic complexes through prior coordination of the NHC to Au(i) and subsequent introduction of the second group 11 metal ion at the bipy donor of the hybrid ligand. The complex [Au(κ(C)-L)(2)]BF(4,)1, has been used as the precursor for the formation of [AuAg(κ-C(Au),κ(2)-N,N′(Ag)-1)(2)](BF(4))(2), 2a, [AuCu(κ-C(Au),κ(2)-N,N′(Cu)-1)(2)](BF(4))(2), 2b and [AuAu′(κ-C(Au/Au′),κ(1)-N(Au/Au′)-1)(2)](BF(4))(2), 3. The Royal Society of Chemistry 2021-10-21 /pmc/articles/PMC9042343/ /pubmed/35497314 http://dx.doi.org/10.1039/d1ra06581e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Kariuki, Benson M.
Platts, James A.
Newman, Paul D.
A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes
title A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes
title_full A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes
title_fullStr A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes
title_full_unstemmed A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes
title_short A hybrid bipy–NHC ligand for the construction of group 11 mixed-metal bimetallic complexes
title_sort hybrid bipy–nhc ligand for the construction of group 11 mixed-metal bimetallic complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042343/
https://www.ncbi.nlm.nih.gov/pubmed/35497314
http://dx.doi.org/10.1039/d1ra06581e
work_keys_str_mv AT kariukibensonm ahybridbipynhcligandfortheconstructionofgroup11mixedmetalbimetalliccomplexes
AT plattsjamesa ahybridbipynhcligandfortheconstructionofgroup11mixedmetalbimetalliccomplexes
AT newmanpauld ahybridbipynhcligandfortheconstructionofgroup11mixedmetalbimetalliccomplexes
AT kariukibensonm hybridbipynhcligandfortheconstructionofgroup11mixedmetalbimetalliccomplexes
AT plattsjamesa hybridbipynhcligandfortheconstructionofgroup11mixedmetalbimetalliccomplexes
AT newmanpauld hybridbipynhcligandfortheconstructionofgroup11mixedmetalbimetalliccomplexes

Ejemplares similares