A comparison of hydrogen release kinetics from 5- and 6-membered 1,2-BN-cycloalkanes

The reaction order and Arrhenius activation parameters for spontaneous hydrogen release from cyclic amine boranes, i.e., BN-cycloalkanes, were determined for 1,2-BN-cyclohexane (1) and 3-methyl-1,2-BN-cyclopentane (2) in tetraglyme. Computational analysis identified a mechanism involving catalytic s...

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Detalles Bibliográficos
Autores principales: Giustra, Zachary X., Chen, Gang, Vasiliu, Monica, Karkamkar, Abhijeet, Autrey, Tom, Dixon, David A., Liu, Shih-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042405/
https://www.ncbi.nlm.nih.gov/pubmed/35497319
http://dx.doi.org/10.1039/d1ra07477f
Descripción
Sumario:The reaction order and Arrhenius activation parameters for spontaneous hydrogen release from cyclic amine boranes, i.e., BN-cycloalkanes, were determined for 1,2-BN-cyclohexane (1) and 3-methyl-1,2-BN-cyclopentane (2) in tetraglyme. Computational analysis identified a mechanism involving catalytic substrate activation by a ring-opened form of 1 or 2 as being consistent with experimental observations.

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