MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation

As an efficient heterogenous N-heterocyclic carbene (NHC) catalyst, MOF-Zn-NHC was used in the aerobic oxidation of aryl aldehydes to their corresponding carbocyclic acids via an anomeric based oxidation. Features such as mild reaction conditions and no need for a co-catalyst or oxidative reagent ca...

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Autores principales: Babaee, Saeed, Zarei, Mahmoud, Zolfigol, Mohammad Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043340/
https://www.ncbi.nlm.nih.gov/pubmed/35492781
http://dx.doi.org/10.1039/d1ra05494e
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author Babaee, Saeed
Zarei, Mahmoud
Zolfigol, Mohammad Ali
author_facet Babaee, Saeed
Zarei, Mahmoud
Zolfigol, Mohammad Ali
author_sort Babaee, Saeed
collection PubMed
description As an efficient heterogenous N-heterocyclic carbene (NHC) catalyst, MOF-Zn-NHC was used in the aerobic oxidation of aryl aldehydes to their corresponding carbocyclic acids via an anomeric based oxidation. Features such as mild reaction conditions and no need for a co-catalyst or oxidative reagent can be considered as the major advantages of the presented method in this study.
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spelling pubmed-90433402022-04-28 MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation Babaee, Saeed Zarei, Mahmoud Zolfigol, Mohammad Ali RSC Adv Chemistry As an efficient heterogenous N-heterocyclic carbene (NHC) catalyst, MOF-Zn-NHC was used in the aerobic oxidation of aryl aldehydes to their corresponding carbocyclic acids via an anomeric based oxidation. Features such as mild reaction conditions and no need for a co-catalyst or oxidative reagent can be considered as the major advantages of the presented method in this study. The Royal Society of Chemistry 2021-11-10 /pmc/articles/PMC9043340/ /pubmed/35492781 http://dx.doi.org/10.1039/d1ra05494e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Babaee, Saeed
Zarei, Mahmoud
Zolfigol, Mohammad Ali
MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
title MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
title_full MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
title_fullStr MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
title_full_unstemmed MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
title_short MOF-Zn-NHC as an efficient N-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
title_sort mof-zn-nhc as an efficient n-heterocyclic carbene catalyst for aerobic oxidation of aldehydes to their corresponding carboxylic acids via a cooperative geminal anomeric based oxidation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043340/
https://www.ncbi.nlm.nih.gov/pubmed/35492781
http://dx.doi.org/10.1039/d1ra05494e
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AT zareimahmoud mofznnhcasanefficientnheterocycliccarbenecatalystforaerobicoxidationofaldehydestotheircorrespondingcarboxylicacidsviaacooperativegeminalanomericbasedoxidation
AT zolfigolmohammadali mofznnhcasanefficientnheterocycliccarbenecatalystforaerobicoxidationofaldehydestotheircorrespondingcarboxylicacidsviaacooperativegeminalanomericbasedoxidation

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