N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety

Ruthenium complexes containing two anilines or its derivatives, cis-[Ru(II)(NH(2)C(6)H(5))(2)(bpy)(2)](2+) ([1](2+)) and cis-[Ru(II)(NH(2)C(6)H(4)(4-CH(3)))(2)(bpy)(2)](2+) ([2](2+)), were oxidized by four molar equivalents of (NH(4))(4)[Ce(IV)(SO(4))(4)]·2H(2)O to give N(1)-phenylcyclohexa-3,5-dien...

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Autores principales: Tomioka, Nozomi, Nanbu, Shinkoh, Misawa-Suzuki, Tomoyo, Nagao, Hirotaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043462/
https://www.ncbi.nlm.nih.gov/pubmed/35494383
http://dx.doi.org/10.1039/d1ra07736h
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author Tomioka, Nozomi
Nanbu, Shinkoh
Misawa-Suzuki, Tomoyo
Nagao, Hirotaka
author_facet Tomioka, Nozomi
Nanbu, Shinkoh
Misawa-Suzuki, Tomoyo
Nagao, Hirotaka
author_sort Tomioka, Nozomi
collection PubMed
description Ruthenium complexes containing two anilines or its derivatives, cis-[Ru(II)(NH(2)C(6)H(5))(2)(bpy)(2)](2+) ([1](2+)) and cis-[Ru(II)(NH(2)C(6)H(4)(4-CH(3)))(2)(bpy)(2)](2+) ([2](2+)), were oxidized by four molar equivalents of (NH(4))(4)[Ce(IV)(SO(4))(4)]·2H(2)O to give N(1)-phenylcyclohexa-3,5-diene-1,2-diimineruthenium(ii) complexes, cis-[Ru(II)(NHC(6)H(4)NC(6)H(5))(bpy)(2)](2+) ([4](2+)) and cis-[Ru(II)(NHC(6)H(3)(4-CH(3))NC(6)H(4)(4-CH(3)))(bpy)(2)](2+) ([5](2+)), respectively, through an N–C bond formation between two aniline ligands cis-coordinated to the ruthenium center.
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spelling pubmed-90434622022-04-28 N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety Tomioka, Nozomi Nanbu, Shinkoh Misawa-Suzuki, Tomoyo Nagao, Hirotaka RSC Adv Chemistry Ruthenium complexes containing two anilines or its derivatives, cis-[Ru(II)(NH(2)C(6)H(5))(2)(bpy)(2)](2+) ([1](2+)) and cis-[Ru(II)(NH(2)C(6)H(4)(4-CH(3)))(2)(bpy)(2)](2+) ([2](2+)), were oxidized by four molar equivalents of (NH(4))(4)[Ce(IV)(SO(4))(4)]·2H(2)O to give N(1)-phenylcyclohexa-3,5-diene-1,2-diimineruthenium(ii) complexes, cis-[Ru(II)(NHC(6)H(4)NC(6)H(5))(bpy)(2)](2+) ([4](2+)) and cis-[Ru(II)(NHC(6)H(3)(4-CH(3))NC(6)H(4)(4-CH(3)))(bpy)(2)](2+) ([5](2+)), respectively, through an N–C bond formation between two aniline ligands cis-coordinated to the ruthenium center. The Royal Society of Chemistry 2021-11-15 /pmc/articles/PMC9043462/ /pubmed/35494383 http://dx.doi.org/10.1039/d1ra07736h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Tomioka, Nozomi
Nanbu, Shinkoh
Misawa-Suzuki, Tomoyo
Nagao, Hirotaka
N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
title N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
title_full N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
title_fullStr N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
title_full_unstemmed N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
title_short N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
title_sort n–c bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043462/
https://www.ncbi.nlm.nih.gov/pubmed/35494383
http://dx.doi.org/10.1039/d1ra07736h
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