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N–C bond formation between two anilines coordinated to a ruthenium center in cis-form affording a 3,5-cyclohexadiene-1,2-diimine moiety
Ruthenium complexes containing two anilines or its derivatives, cis-[Ru(II)(NH(2)C(6)H(5))(2)(bpy)(2)](2+) ([1](2+)) and cis-[Ru(II)(NH(2)C(6)H(4)(4-CH(3)))(2)(bpy)(2)](2+) ([2](2+)), were oxidized by four molar equivalents of (NH(4))(4)[Ce(IV)(SO(4))(4)]·2H(2)O to give N(1)-phenylcyclohexa-3,5-dien...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043462/ https://www.ncbi.nlm.nih.gov/pubmed/35494383 http://dx.doi.org/10.1039/d1ra07736h |