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Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites

Ternary composites have demonstrated better capability than binary composites in enhancing the mechanical properties of the modified epoxy resins and are, therefore, currently under intensive investigation. Herein, we report a novel ternary nanocomposite prepared by filling a binary BPF (bisphenol F...

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Autores principales: Cao, Dehua, Liu, Guangsheng, Chen, Wenting, Lv, Xuefeng, Song, Taize, Zhang, Linyi, Liu, Song, Li, Yi, Wang, Nannan, Zhu, Yanqiu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043543/
https://www.ncbi.nlm.nih.gov/pubmed/35496395
http://dx.doi.org/10.1039/d1ra07136j
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author Cao, Dehua
Liu, Guangsheng
Chen, Wenting
Lv, Xuefeng
Song, Taize
Zhang, Linyi
Liu, Song
Li, Yi
Wang, Nannan
Zhu, Yanqiu
author_facet Cao, Dehua
Liu, Guangsheng
Chen, Wenting
Lv, Xuefeng
Song, Taize
Zhang, Linyi
Liu, Song
Li, Yi
Wang, Nannan
Zhu, Yanqiu
author_sort Cao, Dehua
collection PubMed
description Ternary composites have demonstrated better capability than binary composites in enhancing the mechanical properties of the modified epoxy resins and are, therefore, currently under intensive investigation. Herein, we report a novel ternary nanocomposite prepared by filling a binary BPF (bisphenol F epoxy resin)/SCPs (sugarcane-based carbon powders) matrix with C-coated inorganic fullerene-like tungsten disulfide (IF-WS(2)@C) nanoparticles, and the analysis of its interface synergetic effect using XPS/FTIR. This activated nano-carbon core–shell structure filler is considered an ideal nanofiller and shows the excellent mechanical performance of the ternary composites. XRD, IR, XPS, SEM, and TEM characterizations were applied in investigating this nanocomposite. The improvement of the thermal and mechanical properties demonstrated the enhancement effects of this nanofiller. The results show that the great improvement of the bending modulus of 39.4% increased with the addition of 0.5 wt% IF-WS(2)@C nanoparticles, while 34.1% enhancement of bending strength was obtained with the addition of 0.2 wt% IF-WS(2)@C nanoparticles. The hardness and thermal conductivity were also boosted up to 5.2% and 33.1% with 0.5 wt% addition, respectively. The incorporation of a chemically activated coating may provide a novel means for improving graphite crystallization, which could somehow expand the potential application of IF-WS(2)@C nanoparticles.
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spelling pubmed-90435432022-04-28 Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites Cao, Dehua Liu, Guangsheng Chen, Wenting Lv, Xuefeng Song, Taize Zhang, Linyi Liu, Song Li, Yi Wang, Nannan Zhu, Yanqiu RSC Adv Chemistry Ternary composites have demonstrated better capability than binary composites in enhancing the mechanical properties of the modified epoxy resins and are, therefore, currently under intensive investigation. Herein, we report a novel ternary nanocomposite prepared by filling a binary BPF (bisphenol F epoxy resin)/SCPs (sugarcane-based carbon powders) matrix with C-coated inorganic fullerene-like tungsten disulfide (IF-WS(2)@C) nanoparticles, and the analysis of its interface synergetic effect using XPS/FTIR. This activated nano-carbon core–shell structure filler is considered an ideal nanofiller and shows the excellent mechanical performance of the ternary composites. XRD, IR, XPS, SEM, and TEM characterizations were applied in investigating this nanocomposite. The improvement of the thermal and mechanical properties demonstrated the enhancement effects of this nanofiller. The results show that the great improvement of the bending modulus of 39.4% increased with the addition of 0.5 wt% IF-WS(2)@C nanoparticles, while 34.1% enhancement of bending strength was obtained with the addition of 0.2 wt% IF-WS(2)@C nanoparticles. The hardness and thermal conductivity were also boosted up to 5.2% and 33.1% with 0.5 wt% addition, respectively. The incorporation of a chemically activated coating may provide a novel means for improving graphite crystallization, which could somehow expand the potential application of IF-WS(2)@C nanoparticles. The Royal Society of Chemistry 2021-11-17 /pmc/articles/PMC9043543/ /pubmed/35496395 http://dx.doi.org/10.1039/d1ra07136j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Cao, Dehua
Liu, Guangsheng
Chen, Wenting
Lv, Xuefeng
Song, Taize
Zhang, Linyi
Liu, Song
Li, Yi
Wang, Nannan
Zhu, Yanqiu
Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
title Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
title_full Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
title_fullStr Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
title_full_unstemmed Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
title_short Chemically activated core–shell structured IF-WS(2)@C nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
title_sort chemically activated core–shell structured if-ws(2)@c nanoparticles enhance sugarcane-based carbon/epoxy nanocomposites
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043543/
https://www.ncbi.nlm.nih.gov/pubmed/35496395
http://dx.doi.org/10.1039/d1ra07136j
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