Cargando…
Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis
With the renaissance of chemical electrosynthesis in the last decade, the electrochemistry of hypervalent iodine compounds has picked up the pace and achieved significant improvements. By employing traceless electrons instead of stoichiometric oxidants as the alternative clean “reagents”, many hyper...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043554/ https://www.ncbi.nlm.nih.gov/pubmed/35494647 http://dx.doi.org/10.3389/fchem.2022.883474 |
_version_ | 1784694907196145664 |
---|---|
author | Chen, Chaoyue Wang, Xin Yang, Tinghai |
author_facet | Chen, Chaoyue Wang, Xin Yang, Tinghai |
author_sort | Chen, Chaoyue |
collection | PubMed |
description | With the renaissance of chemical electrosynthesis in the last decade, the electrochemistry of hypervalent iodine compounds has picked up the pace and achieved significant improvements. By employing traceless electrons instead of stoichiometric oxidants as the alternative clean “reagents”, many hypervalent iodine compounds were efficiently electro-synthesized via anodic oxidation methods and utilized as powerful redox mediators triggering valuable oxidative coupling reactions in a more sustainable way. This minireview gives an up-to-date overview of the recent advances during the past 3 years, encompassing enhanced electrosynthesis technologies, novel synthetic applications, and ideas for improving reaction sustainability. |
format | Online Article Text |
id | pubmed-9043554 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-90435542022-04-28 Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis Chen, Chaoyue Wang, Xin Yang, Tinghai Front Chem Chemistry With the renaissance of chemical electrosynthesis in the last decade, the electrochemistry of hypervalent iodine compounds has picked up the pace and achieved significant improvements. By employing traceless electrons instead of stoichiometric oxidants as the alternative clean “reagents”, many hypervalent iodine compounds were efficiently electro-synthesized via anodic oxidation methods and utilized as powerful redox mediators triggering valuable oxidative coupling reactions in a more sustainable way. This minireview gives an up-to-date overview of the recent advances during the past 3 years, encompassing enhanced electrosynthesis technologies, novel synthetic applications, and ideas for improving reaction sustainability. Frontiers Media S.A. 2022-04-13 /pmc/articles/PMC9043554/ /pubmed/35494647 http://dx.doi.org/10.3389/fchem.2022.883474 Text en Copyright © 2022 Chen, Wang and Yang. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Chen, Chaoyue Wang, Xin Yang, Tinghai Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
title | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
title_full | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
title_fullStr | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
title_full_unstemmed | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
title_short | Recent Updates on Electrogenerated Hypervalent Iodine Derivatives and Their Applications as Mediators in Organic Electrosynthesis |
title_sort | recent updates on electrogenerated hypervalent iodine derivatives and their applications as mediators in organic electrosynthesis |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043554/ https://www.ncbi.nlm.nih.gov/pubmed/35494647 http://dx.doi.org/10.3389/fchem.2022.883474 |
work_keys_str_mv | AT chenchaoyue recentupdatesonelectrogeneratedhypervalentiodinederivativesandtheirapplicationsasmediatorsinorganicelectrosynthesis AT wangxin recentupdatesonelectrogeneratedhypervalentiodinederivativesandtheirapplicationsasmediatorsinorganicelectrosynthesis AT yangtinghai recentupdatesonelectrogeneratedhypervalentiodinederivativesandtheirapplicationsasmediatorsinorganicelectrosynthesis |