Cargando…

Metal-free catalytic hydrocarboxylation of hexafluorobut-2-yne

An efficient method for stereoselective synthesis of trifluorinated enol esters catalyzed by base was introduced. The DFT calculations and experimental results both supported the nucleophilic addition process. The protocol featured mild reaction conditions and showed a wide functional group toleranc...

Descripción completa

Detalles Bibliográficos
Autores principales: Zeng, Ji-Jun, Zhao, Bo, Tang, Xiao-Bo, Han, Sheng, Yang, Zhi-Qiang, Liu, Ze-Peng, Zhang, Wei, Lu, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044190/
https://www.ncbi.nlm.nih.gov/pubmed/35493246
http://dx.doi.org/10.1039/d1ra06526b